N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions | |
Department | 绿色化学研究发展中心 |
Cui XJ(崔新江); Zhang Y(张妍); Deng YQ(邓友全); Shi F(石峰); Shi F(石峰) | |
The second department | osso国家重点实验室 |
2014 | |
Source Publication | Chemical Communications |
ISSN | 1359-7345 |
Volume | 50Issue:88Pages:13521-13524 |
Abstract | An active Pd/ZrCuOx catalyst was prepared for the reductive amination of CO2. The N-methylation of amines and nitro compounds with CO2/H2 can be realized with up to 97% yield under relatively mild reaction conditions. N-Formylation becomes the main reaction if the reaction was performed under milder conditions or using Pd/ZnZrOx as the catalyst. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c4cc05119j |
Indexed By | SCI |
If | 6.834 |
Language | 英语 |
Funding Project | 纳米催化课题组;绿色催化课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/7112 |
Collection | 绿色化学研究发展中心 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Shi F(石峰) |
Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Cui XJ,Zhang Y,Deng YQ,et al. N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions[J]. Chemical Communications,2014,50(88):13521-13524. |
APA | Cui XJ,Zhang Y,Deng YQ,Shi F,&石峰.(2014).N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions.Chemical Communications,50(88),13521-13524. |
MLA | Cui XJ,et al."N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions".Chemical Communications 50.88(2014):13521-13524. |
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c4cc05119j-published(1459KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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