| Base-promoted synthesis of coumarins from salicylaldehydes and aryl-substituted 1,1-dibromo-1-alkenes under transition-metal-free conditions | |
| Department | OSSO国家重点实验室 |
Liu JM(刘建明)1; Zhang X(张欣)1; Shi LJ(石利军)2; Liu MW(刘慕文)1; Yue YY(岳媛媛)1; Li FW(李福伟)2 ; Zhuo KL(卓克垒)1; Liu JM(刘建明); Li FW(李福伟); Zhuo KL(卓克垒)
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| 2014 | |
| Source Publication | Chemical Communications
 |
| ISSN | 1359-7345 |
| Volume | 50Issue:69Pages:9887-9890 |
| Abstract | Facile synthesis of coumarin via the tandem reaction of salicylaldehyde with aryl-substituted 1,1-dibromo-1-alkene was developed. This new protocol proceeds smoothly under mild and transition-metal-free conditions, it allows rapid access to coumarins containing various heteroatoms that are more difficult to prepare by traditional methods. Based on the isolated intermediate of 4-(diethylamino)-3-phenylchroman-2-one and detailed mechanistic studies, a credible tandem pathway was proposed. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c4cc04377d |
| Funding Organization | National Natural Science Foundation of China (21103044;21173070;21205029);Project funded by China Postdoctoral Science Foundation, and Plan for Scientific Innovation Talent of Henan Province (No. 124200510014) |
| Indexed By | SCI |
| If | 6.834 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/7054 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Liu JM(刘建明); Li FW(李福伟); Zhuo KL(卓克垒) |
| Affiliation | 1.Henan Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Green Chem Media & React,Collaborat Innov, Xinxiang 453007, Henan, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Liu JM,Zhang X,Shi LJ,et al. Base-promoted synthesis of coumarins from salicylaldehydes and aryl-substituted 1,1-dibromo-1-alkenes under transition-metal-free conditions[J]. Chemical Communications,2014,50(69):9887-9890. |
| APA | Liu JM.,Zhang X.,Shi LJ.,Liu MW.,Yue YY.,...&卓克垒.(2014).Base-promoted synthesis of coumarins from salicylaldehydes and aryl-substituted 1,1-dibromo-1-alkenes under transition-metal-free conditions.Chemical Communications,50(69),9887-9890. |
| MLA | Liu JM,et al."Base-promoted synthesis of coumarins from salicylaldehydes and aryl-substituted 1,1-dibromo-1-alkenes under transition-metal-free conditions".Chemical Communications 50.69(2014):9887-9890. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 刘建明，石利军 CC.pdf（1461KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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