| Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions | |
| Department | OSSO国家重点实验室 |
Wang WL(汪文龙)1,2; Zheng AM(郑安民)3; Zhao PQ(赵培庆)1 ; Xia CG(夏春谷)1; Li FW(李福伟)1,4; Li FW(李福伟)
| |
| The second department | erc国家工程研究中心 |
| 2014 | |
| Source Publication | ACS Catalysis
 |
| ISSN | 2155-5435 |
| Volume | 4Issue:1Pages:321-327 |
| Abstract | The synthetic control and functions of porous organic polymers (POPs) with N-heterocyclic carbene gold(I) (Au-NHC@POPs) are described in this article. A series of Au-NHC@POPs with tunable physical properties such as surface area and pore size distribution were first synthesized via Sonogashira chemistry by differing monomer strut lengths and concentration during polymerization; a controllable transition from nonporous to microporous and the coexistence of micro- and mesoporous structures in the framework were realized by varying the monomer concentration. To explain this phenomenon, we put forward a model assumption of a branch-branch cross effect. Additionally, Au-NHC@POPs1 was found to have superior catalytic activity in alkyne hydration reactions, and the catalyst could be used six times with a slight loss of activity. |
| Keyword | N-heterocyclic Carbene Porous Organic Polymers Synthetic Control Alkyne Hydration Cross-coupling |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/cs400983y |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21002106;21133011) |
| Indexed By | SCI |
| If | 9.312 |
| Language | 英语 |
| Funding Project | 均相催化课题组;催化新工艺研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/7023 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Li FW(李福伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Chinese Acad Sci, Wuhan Ctr Magnet Resonance, Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Suzhou Inst Nanotech & NanoBion, Suzhou 215123, Peoples R China |
| Recommended Citation GB/T 7714 | Wang WL,Zheng AM,Zhao PQ,et al. Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions[J]. ACS Catalysis,2014,4(1):321-327. |
| APA | Wang WL,Zheng AM,Zhao PQ,Xia CG,Li FW,&李福伟.(2014).Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions.ACS Catalysis,4(1),321-327. |
| MLA | Wang WL,et al."Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions".ACS Catalysis 4.1(2014):321-327. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Wang WL ACS Catal.pd（1414KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment