Application of beta-cyclodextrin-modified, carbon nanotube-reinforced hollow fiber to solid-phase microextraction of plant hormones | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Song XY(宋昕玥)1,2; Ha W(哈伟)1; Chen J(陈娟)1; Shi YP(师彦平)1; Chen J(陈娟); Shi YP(师彦平) | |
2014 | |
Source Publication | Journal of Chromatography A |
ISSN | 0021-9673 |
Volume | 1374Pages:23-30 |
Abstract | A new, efficient, and environmental friendly solid-phase microextraction (SPME) medium based on β-cyclodextrin (β-CD)-modified carbon nanotubes (CNTs) and a hollow fiber (HF) was prepared. Functionalized β-CD was covalently linked to the surface of the carboxylic CNTs and then the obtained nanocomposite was immobilized into the wall pores of HFs under ultrasonic-assisted effect. The scanning electron microscope was used to inspect surface characteristics of fibers, demonstrating the presence of nanocomposites in their wall pores. The reinforced HF was employed in SPME, and its extraction performance was evaluated by analyzing 1-naphthaleneacetic acid (NAA) and 2-naphthoxyacetic acid (2-NOA) in vegetables. Without any tedious clean-up procedure, analytes were extracted from the sample to the adsorbent and organic solvent immobilized in HFs and then desorbed in acetonitrile prior to chromatographic analysis. Under the optimized extraction conditions, the method provided 275- and283-fold enrichment factors of NAA and 2-NOA, low limits of detection and quantification (at an ng g−1 level), satisfactory spiked recoveries, good inter-fiber repeatability, and batch-to-batch reproducibility. The selectivity of the developed fiber was investigated to three structurally similar compounds and two reference compounds with recognition coefficients up to 3.18. The obtained results indicate that the newly developed fiber is a feasible, selective, green, and cost-effective microextraction medium and could be successfully applied for extraction and determination of naphthalene-derived plant hormones in complex matrices. |
Keyword | Carbon Nanotubes Beta-cyclodextrin Hollow Fiber Solid-phase Microextraction Plant Hormones Tomato Analysis |
Subject Area | 分析化学与药物化学 |
DOI | 10.1016/j.chroma.2014.11.029 |
Funding Organization | the National Natural Science Foundationof China (Nos. 21105106;21375136);the Scholar Program of West Light Project;Chinese Academy of Sciences |
Indexed By | SCI |
If | 4.169 |
Language | 英语 |
Funding Project | 药物化学成分研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/6981 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Chen J(陈娟); Shi YP(师彦平) |
Affiliation | 1.Key Laboratory of Chemistry of Northwestern Plant Resources of the CAS and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PR China 2.University of Chinese Academy of Sciences, Beijing 100039, PR China |
Recommended Citation GB/T 7714 | Song XY,Ha W,Chen J,et al. Application of beta-cyclodextrin-modified, carbon nanotube-reinforced hollow fiber to solid-phase microextraction of plant hormones[J]. Journal of Chromatography A,2014,1374:23-30. |
APA | Song XY,Ha W,Chen J,Shi YP,陈娟,&师彦平.(2014).Application of beta-cyclodextrin-modified, carbon nanotube-reinforced hollow fiber to solid-phase microextraction of plant hormones.Journal of Chromatography A,1374,23-30. |
MLA | Song XY,et al."Application of beta-cyclodextrin-modified, carbon nanotube-reinforced hollow fiber to solid-phase microextraction of plant hormones".Journal of Chromatography A 1374(2014):23-30. |
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