| Highly efficient hydrogen production from formaldehyde over Ag/gamma-Al2O3 catalyst at room temperature | |
| Department | ERC国家工程研究中心 |
Li YW(李雅雯)1,2; Chen T(陈涛)2; Wang T(王腾)2; Zhang YP(张应鹏)1; Lu GX(吕功煊)2 ; Bi YP(毕迎普)2; Zhang YP(张应鹏); Bi YP(毕迎普)
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| The second department | osso国家重点实验室 |
| 2014 | |
| Source Publication | International Journal of Hydrogen Energy
 |
| ISSN | 0360-3199 |
| Volume | 39Issue:17Pages:9114-9120 |
| Abstract | Herein, we demonstrate a simple and efficient process for generating hydrogen from the formaldehyde (HCHO) aqueous solution catalyzed by Ag nanoparticles dispersed on high specific surface area γ-Al2O3 at room temperature. Moreover, this Ag/γ-Al2O3 catalyst exhibits much higher capability and stability for hydrogen production than unsupported Ag nanoparticles. By further optimizing the structure, component, and amounts of Ag/γ-Al2O3 catalysts as well as reaction parameters such as reaction atmosphere, formaldehyde concentrations, and NaOH concentrations, the hydrogen generation rate could be greatly increased and maintained for ten hours without any decay. It may provide a general and favorable strategy for the fabrication of highly reactive and stable metal catalyst for the hydrogen production from organic aldehyde solutions. |
| Keyword | Formaldehyde Hydrogen Ag/gamma-al2o3 Catalysis |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.ijhydene.2014.03.257 |
| Funding Organization | the “Hundred Talents Program” of the Chinese Academy of Science;the National Natural Science Foundation of China (21273255;21303232) |
| Indexed By | SCI |
| If | 3.313 |
| Language | 英语 |
| Funding Project | 能源与环境纳米催化材料组;环境催化与氢能源研究组;环境催化与清洁能源研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/6916 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Zhang YP(张应鹏); Bi YP(毕迎普) |
| Affiliation | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Li YW,Chen T,Wang T,et al. Highly efficient hydrogen production from formaldehyde over Ag/gamma-Al2O3 catalyst at room temperature[J]. International Journal of Hydrogen Energy,2014,39(17):9114-9120. |
| APA | Li YW.,Chen T.,Wang T.,Zhang YP.,Lu GX.,...&毕迎普.(2014).Highly efficient hydrogen production from formaldehyde over Ag/gamma-Al2O3 catalyst at room temperature.International Journal of Hydrogen Energy,39(17),9114-9120. |
| MLA | Li YW,et al."Highly efficient hydrogen production from formaldehyde over Ag/gamma-Al2O3 catalyst at room temperature".International Journal of Hydrogen Energy 39.17(2014):9114-9120. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| IH-1.pdf（1174KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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