| Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes | |
| Department | OSSO国家重点实验室 |
Hu HY(胡红岩)1 ; Jiao ZB(焦正波)1; Ye JH(叶金花)2; Lu GX(吕功煊)1; Bi YP(毕迎普)1; Bi YP(毕迎普)
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| The second department | erc国家工程研究中心 |
| 2014 | |
| Source Publication | Nano Energy
 |
| ISSN | 2211-2855 |
| Volume | 8Pages:103-109 |
| Abstract | Herein, we demonstrate that hollow Pd nanotubes could serve as a highly efficient and convenient catalyst for inhibiting Cannizzaro reaction and facilitating hydrogen generation from alkaline formaldehyde solution at room temperature. Moreover, this hollow nanostructure exhibits much higher capability and stability for hydrogen production than conventional Pd nanoparticles. By further optimizing the reaction parameters such as reaction temperature, formaldehyde concentrations, and NaOH concentrations, the hydrogen generation rates could be further increased. Moreover, except for formaldehyde, other aldehydes, including acetaldehyde, propanal, and benaldehyde, could also produce hydrogen with high efficiencies. Owing to its high efficiency at room temperature, this Pd nanotube based hydrogen generation reaction may serve as an alternate hydrogen supply candidate. |
| Keyword | Cannizzaro Reaction Hydrogen Pd Nanotube Catalysis |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.nanoen.2014.05.015 |
| Funding Organization | the “Hundred Talents Program” of the Chinese Academy of Science;National Natural Science Foundation of China (21273255;21303232) |
| Indexed By | SCI |
| If | 10.325 |
| Language | 英语 |
| Funding Project | 能源与环境纳米催化材料组;环境催化与氢能源研究组;环境催化与清洁能源研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/6915 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Bi YP(毕迎普) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, Res Unit Environm Remediat Mat, Tsukuba, Ibaraki 3050047, Japan |
| Recommended Citation GB/T 7714 | Hu HY,Jiao ZB,Ye JH,et al. Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes[J]. Nano Energy,2014,8:103-109. |
| APA | Hu HY,Jiao ZB,Ye JH,Lu GX,Bi YP,&毕迎普.(2014).Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes.Nano Energy,8,103-109. |
| MLA | Hu HY,et al."Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes".Nano Energy 8(2014):103-109. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Nano energy.pdf（1917KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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