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Grafting zwitterionic polymer brushes via electrochemical surface-initiated atomic-transfer radical polymerization for anti-fouling applications
Department固体润滑国家重点实验室
Zhao WW(赵文文)1,2; Ye Q(叶谦)1; Hu HY(胡海媛)1; Wang XL(王晓龙)1; Zhou F(周峰)1; Ye Q(叶谦); Zhou F(周峰)
2014
Source PublicationJournal of Materials Chemistry B
ISSN2050-750X
Volume2Issue:33Pages:5352-5357
AbstractZwitterionic polymer brushes based on sulfobetaine vinylimidazole (pSBVI) were successfully grafted to silicon substrates by electrochemical surface-initiated atomic-transfer radical polymerization (e-SIATRP), and exhibited excellent anti-fouling activities because of the presence of the two bactericidal functional groups, imidazolium and sulfonate. Various characterization techniques, including atomic force microscopy, X-ray photoelectron spectroscopy and use of a quartz crystal microbalance, were employed to characterize the polymer brush-modified silicon substrates. Subsequently, the anti-bacterial and anti-biofouling activities of the polymer brush substrates were evaluated. The experimental results showed that the pSBVI effectively resisted the adhesion of Nannochloropsis maritima and showed good anti-bacterial activity against Escherichia coli. In addition, in comparison with poly(vinylimidazole) brushmodified substrates and the bare substrate, the pSBVI-based materials also exhibited excellent antiadsorption performance against both bovine serum albumin and lysozyme.
Subject Area材料科学与物理化学
DOI10.1039/c4tb00816b
Funding OrganizationKey Project of National Natural Science Foundation of China (21125316;21204095;51203173);the Key Research Program of the Chinese Academy of Sciences (KJZD-EW-M01)
Indexed BySCI
If4.726
Language英语
Funding Project材料表面与界面行为研究组
compositor第一作者单位
Citation statistics
Cited Times:71[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/6859
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorYe Q(叶谦); Zhou F(周峰)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhao WW,Ye Q,Hu HY,et al. Grafting zwitterionic polymer brushes via electrochemical surface-initiated atomic-transfer radical polymerization for anti-fouling applications[J]. Journal of Materials Chemistry B,2014,2(33):5352-5357.
APA Zhao WW.,Ye Q.,Hu HY.,Wang XL.,Zhou F.,...&周峰.(2014).Grafting zwitterionic polymer brushes via electrochemical surface-initiated atomic-transfer radical polymerization for anti-fouling applications.Journal of Materials Chemistry B,2(33),5352-5357.
MLA Zhao WW,et al."Grafting zwitterionic polymer brushes via electrochemical surface-initiated atomic-transfer radical polymerization for anti-fouling applications".Journal of Materials Chemistry B 2.33(2014):5352-5357.
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