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Composition, microstructure, and properties of CrNx films deposited using medium frequency magnetron sputtering
Department固体润滑国家重点实验室
Kong QH(孔庆花); Ji L(吉利); Li HX(李红轩); Liu XH(刘晓红); Wang YJ(王永军); Chen JM(陈建敏); Zhou HD(周惠娣)
2011
Source PublicationApplied Surface Science
ISSN0169-4332
Volume257Issue:无期Pages:2269-2274
AbstractCrNx films were deposited on stainless steel and Si (1 1 1) substrates via medium frequency magnetron sputtering in aN2 +Armixed atmosphere. The influence ofN2 content on the deposition rate, composition, microstructure, mechanical and tribological properties of the as-deposited films was investigated by means of the X-ray photoelectron spectrometry (XPS), X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), nanoindentation and tribometer testing. It was found that the N atomic concentration increased and the phase transformed fromamixture of Cr2N+ Cr(N) to single-phase Cr2N, and then Cr2N+ CrN to pure CrN phase with the increase of N2 content. The Cr 2p3/2 and N 1s of XPS spectra also confirmed the evolution of phase.Accordingly, allfilms exhibited a typical columnar structure which lies in the zone T of Thornton Model. The mixed Cr2N and Cr(N) phases showed low hardness and high friction coefficient. Cr2N possessed higher hardness than CrN while CrN exhibited lower friction coefficient.
KeywordCrnx FIlms Medium Frequency Magnetron Sputtering N2 Content Microstructure Mechanical Properties Tribological Properties
Subject Area材料科学与物理化学
Funding Organizationthe National Natural Science Foundation of China (Grant NO.50705093);the Innovative Group Foundation from NSFC (Grant NO.50421502)
Indexed BySCI
Language英语
Funding Project磨损和表面工程组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/670
Collection固体润滑国家重点实验室(LSL)
中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
Corresponding AuthorLi HX(李红轩)
Recommended Citation
GB/T 7714
Kong QH,Ji L,Li HX,et al. Composition, microstructure, and properties of CrNx films deposited using medium frequency magnetron sputtering[J]. Applied Surface Science,2011,257(无期):2269-2274.
APA 孔庆花.,吉利.,李红轩.,刘晓红.,王永军.,...&周惠娣.(2011).Composition, microstructure, and properties of CrNx films deposited using medium frequency magnetron sputtering.Applied Surface Science,257(无期),2269-2274.
MLA 孔庆花,et al."Composition, microstructure, and properties of CrNx films deposited using medium frequency magnetron sputtering".Applied Surface Science 257.无期(2011):2269-2274.
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