| Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications | |
| Department | 清洁能源化学与材料实验室 |
Agnieszka Zielinska1,2; Marcin Leonowicz2; Li HG(李洪光)3 ; Takashi Nakanishi1,2; Li HG(李洪光)
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| 2014 | |
| Source Publication | Current Opinion in Colloid and Interface Science
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| ISSN | 1359-0294 |
| Volume | 19Issue:2Pages:131-139 |
| Abstract | Organic and polymeric molecules based on pi-conjugated units represent an important class of components for optical and optoelectronic functionalized soft materials. Inspired by the innovative molecular design made by synthetic chemists, new functions and applications of pi-conjugated molecules are continuously emerging. However, a challenge that remains is to soften these molecules. Alkylation is a commonly employed synthetic strategy to achieve functionalization in order to improve processability, i.e., solubility in volatile solvents, for better utilization in the rapidly-developing field of organic electronics. In addition it is recognized as a powerful strategy to tune the interaction among the pi-conjugated moieties. In a different interpretation of alkylation, alkylated-pi compounds can be viewed as a class of hydrophobic amphiphiles, since the rigid pi-conjugated moiety and flexible alkyl chains are intrinsically immiscible. Recent studies have shown that such compounds can form a variety of self-organized solid and thermotropic liquid crystalline structures as well as nonassembled liquid forms depending upon the position, number and kinds of attached alkyl chains. Here, we present a brief overview of recent developments of alkylated-pi chemistry, with an emphasis on the relationships between molecular design, self-assembly behavior and applications in optical and optoelectronic devices. We hope this review can serve as a guide and reference for people working in different research areas, including self-assembly and colloid sciences, synthetic and materials chemistry was well as organic electronics. |
| Keyword | Alkyl Chains Hydrophobic Amphiphiles Organic Electronics Pi-conjugated Compounds Self-assembly |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1016/j.cocis.2014.03.007 |
| Funding Organization | KAKENHI (23685033;25620069;25104011) from MEXT, Japan, Nagase Science and Technology Foundation;the Hundred Talents Program of Chinese Academy of Sciences (Y20245YBR1) |
| Indexed By | SCI |
| If | 5.840 |
| Language | 英语 |
| Funding Project | 柔性有机太阳能电池研究组 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/6618 |
| Collection | 清洁能源化学与材料实验室 |
| Corresponding Author | Takashi Nakanishi; Li HG(李洪光) |
| Affiliation | 1.Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan 2.Warsaw Univ Technol, Fac Mat Sci & Engn, PL-02507 Warsaw, Poland 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Agnieszka Zielinska,Marcin Leonowicz,Li HG,et al. Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications[J]. Current Opinion in Colloid and Interface Science,2014,19(2):131-139. |
| APA | Agnieszka Zielinska,Marcin Leonowicz,Li HG,Takashi Nakanishi,&李洪光.(2014).Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications.Current Opinion in Colloid and Interface Science,19(2),131-139. |
| MLA | Agnieszka Zielinska,et al."Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications".Current Opinion in Colloid and Interface Science 19.2(2014):131-139. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 21 COCIS.pdf（1553KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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