| Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock | |
| Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Li Q(李欠)1 ; Wang ZZ(王振忠)1,2; Xu J(徐健)1,2; Yue Y(岳莹)1; Shao SJ(邵士俊)1; Shao SJ(邵士俊)
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| 2014 | |
| Source Publication | RSC Advances
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| ISSN | 2046-2069 |
| Volume | 4Issue:65Pages:34470-34473 |
| Abstract | Calix[4]pyrrole based anion receptors 1 and 2 have been synthesized. The recognition and sensing process has been studied by UV-vis absorption and partial 1H NMR titration experiments. Receptor 1 could act as a colorimetric sensor for fluoride anions, and receptor 2 could recognize F- and AcO- anions in DMSO solvent. Moreover, this type of sensing behaviour could successfully mimic a molecular level keypad lock stimulated by the two sequential chemical inputs (AcO- and F-), which has the potential for application in security devices. |
| Subject Area | 分析化学与药物化学 |
| DOI | 10.1039/c4ra05499g |
| Funding Organization | the National Natural Science Foundation of China (20972170;21275150);the Funds for Distinguished Young Scientists of Gansu (1210RJDA013);the Natural Science Foundation of Gansu province (1107RJYA069) |
| Indexed By | SCI |
| If | 3.840 |
| Language | 英语 |
| Funding Project | 药物分子识别研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/6579 |
| Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| Corresponding Author | Shao SJ(邵士俊) |
| Affiliation | 1.Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China 2.University of Chinese Academy of Sciences, Beijing 100039, P. R. China |
| Recommended Citation GB/T 7714 | Li Q,Wang ZZ,Xu J,et al. Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock[J]. RSC Advances,2014,4(65):34470-34473. |
| APA | Li Q,Wang ZZ,Xu J,Yue Y,Shao SJ,&邵士俊.(2014).Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock.RSC Advances,4(65),34470-34473. |
| MLA | Li Q,et al."Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock".RSC Advances 4.65(2014):34470-34473. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2014 RSC Advances.pd（750KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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