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High Clay-Content Attapulgite/Poly(acrylic acid) Nanocomposite Hydrogel via Surface-Initiated Redox Radical Polymerization with Modified Attapulgite Nanorods as Initiator and Cross-Linker
Department环境材料与生态化学研究发展中心
Zhu LX(朱龙祥)1; Liu P(刘鹏)1; Wang AQ(王爱勤)2; Liu P(刘鹏)
2014
Source PublicationIndustrial and Engineering Chemistry Research
ISSN0888-5885
Volume53Issue:5Pages:2067-2071
Abstract

Attapulgite/poly(acrylic acid) nanocomposite (ATP/PAA) hydrogels with high clay content of around 90% have been synthesized by a novel surface-initiated redox radical solution polymerization of acrylic acid (AA) with the 3-aminopropyltriethoxysilane (APTES) modified attapulgite nanorods (ATP-NH2) as initiator and the 3-methacryloxypropyltrimethoxysilane (MPTMS) modified attapulgite nanorods (ATP-C═C) as cross-linker. High inorganic-content nanocomposite (ATP/PAA) hydrogel with a three-dimensional network structure was obtained via the linkage of the different functional attapulgite nanorods with the grafted poly(acrylic acid) (PAA) chains. Both the two kinds of the functional attapulgite nanorods acted as the cross-linking sites in the nanocomposite hydrogel. Due to its unique structure, a remarkably high adsorption capacity of the cationic dye (methylene blue (MB)) of 308.0 mg/g was achieved when the ATP/PAA nanocomposite hydrogel was used as the adsorbent for water treatment.

Subject Area环境材料与生态化学
DOI10.1021/ie402878w
Indexed BySCI
If2.587
Language英语
Funding Project功能复合材料组
compositor第二作者单位
Citation statistics
Cited Times:33[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/6557
Collection环境材料与生态化学研究发展中心
Corresponding AuthorLiu P(刘鹏)
Affiliation1.State Key Laboratory of Applied Organic Chemistry and Institute of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
2.Center of Xuyi Attapulgite Applied Technology, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, 730000, China
Recommended Citation
GB/T 7714
Zhu LX,Liu P,Wang AQ,et al. High Clay-Content Attapulgite/Poly(acrylic acid) Nanocomposite Hydrogel via Surface-Initiated Redox Radical Polymerization with Modified Attapulgite Nanorods as Initiator and Cross-Linker[J]. Industrial and Engineering Chemistry Research,2014,53(5):2067-2071.
APA Zhu LX,Liu P,Wang AQ,&刘鹏.(2014).High Clay-Content Attapulgite/Poly(acrylic acid) Nanocomposite Hydrogel via Surface-Initiated Redox Radical Polymerization with Modified Attapulgite Nanorods as Initiator and Cross-Linker.Industrial and Engineering Chemistry Research,53(5),2067-2071.
MLA Zhu LX,et al."High Clay-Content Attapulgite/Poly(acrylic acid) Nanocomposite Hydrogel via Surface-Initiated Redox Radical Polymerization with Modified Attapulgite Nanorods as Initiator and Cross-Linker".Industrial and Engineering Chemistry Research 53.5(2014):2067-2071.
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