| Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 绿色化学研究发展中心 |
| Liu JH(刘俊华); Wang F(王芳); Gu ZG(顾正贵); Xu XL(徐贤伦) | |
| 2009 | |
| Source Publication | Catalysis Communications
 |
| ISSN | 1566-7367 |
| Volume | 10Pages:868-871 |
| Abstract | A hybrid complex Zr(PO4)(AgHPO4) was prepared by ion-exchange and was determined using elemental analysis, X-ray diffraction (XRD), Fourier transformed-infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and other instruments. Its catalytic activity was examined on the oxidation of styrene using t-butylhydroperoxide (TBHP) as oxidant under argon atmosphere, this system showed good epoxidation selectivity, the other factors, such as solvent, reaction time, concentrations of oxidant and catalyst, also have been investigated and reaction conditions are optimized. It is a novel highly active/selective and reusable heterogeneous catalyst for styrene epoxidation, while this catalytic system showed no epoxidation selectivity but good enol selectivity for cycloolefins with allylic H. |
| Keyword | Epoxidation Styrene Silver Zirconium Phosphates |
| Subject Area | 物理化学 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 ; 精细石油化工催化课题组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/640 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 绿色化学研究发展中心 |
| Corresponding Author | Liu JH(刘俊华) |
| Recommended Citation GB/T 7714 | Liu JH,Wang F,Gu ZG,et al. Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange[J]. Catalysis Communications,2009,10:868-871. |
| APA | 刘俊华,王芳,顾正贵,&徐贤伦.(2009).Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange.Catalysis Communications,10,868-871. |
| MLA | 刘俊华,et al."Styrene epoxidation over Ag-c-ZrP catalyst prepared by ion-exchange".Catalysis Communications 10(2009):868-871. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| B9_Catal.Commun.2009（279KB） | 开放获取 | License | View Application Full Text | |||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment