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冠醚配位作用的热力学性质——水液溶中1,4,7,10,13,16-六氧杂环十八烷与若干钾盐配位作用的负离子效应
Department非现建制
刘育; 胡靖
1987
Source Publication物理化学学报
ISSN1000-6818
Volume3Issue:1Pages:11-15
Abstract本文用量热滴定法测定了1,4,7,10,13,16-六氧杂环十八烷(以下称18-冠-6)与KCl, KBr, KI, KClO4, KNO3, KBrO3及K2S2O3共八种钾盐在水溶液中, 25 ℃时的配位作用, 直接计算了配合物稳定常数及配位反应热。实验结果表明, 18-冠-6与KNO3, K2S2O3形成的配位化合物, 其稳定常数最高。讨论了阴离子对配位稳定性的影响。
Subject Area物理化学
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/6102
Collection非现建制
Recommended Citation
GB/T 7714
刘育,胡靖. 冠醚配位作用的热力学性质——水液溶中1,4,7,10,13,16-六氧杂环十八烷与若干钾盐配位作用的负离子效应[J]. 物理化学学报,1987,3(1):11-15.
APA 刘育,&胡靖.(1987).冠醚配位作用的热力学性质——水液溶中1,4,7,10,13,16-六氧杂环十八烷与若干钾盐配位作用的负离子效应.物理化学学报,3(1),11-15.
MLA 刘育,et al."冠醚配位作用的热力学性质——水液溶中1,4,7,10,13,16-六氧杂环十八烷与若干钾盐配位作用的负离子效应".物理化学学报 3.1(1987):11-15.
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