Concise Total Synthesis of (+)-Aspergillide B | |
Department | 羰基合成与选择氧化国家重点实验室 |
Liu J(刘剑); Xu K(许可); He JM(何金梅); Zhang L(张玲); Pan XF(潘鑫复); She XG(厍学功) | |
2009 | |
Source Publication | Journal of Organic Chemistry |
ISSN | 0022-3263 |
Volume | 74Issue:14Pages:5063-5066 |
Abstract | An efficient total synthesis of (+)-aspergillide B has been achieved, which features the C-glycosylation reaction for constructing the 2,6-trans-substituted pyran core, a highly effective four-step sequence without purification to produce the key intermediate 13 and an advantegous E-selective Julia-Kocienski olefination on a highly elaborate substrate. The synthesis confirmed the revised structure of aspergillide B by Uenishi. |
Subject Area | 物理化学 |
Funding Organization | the NSFC (QT program, 20872054;20732002);NCET-05-0879 |
Indexed By | SCI |
Language | 英语 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/537 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | She XG(厍学功) |
Recommended Citation GB/T 7714 | Liu J,Xu K,He JM,et al. Concise Total Synthesis of (+)-Aspergillide B[J]. Journal of Organic Chemistry,2009,74(14):5063-5066. |
APA | 刘剑,许可,何金梅,张玲,潘鑫复,&厍学功.(2009).Concise Total Synthesis of (+)-Aspergillide B.Journal of Organic Chemistry,74(14),5063-5066. |
MLA | 刘剑,et al."Concise Total Synthesis of (+)-Aspergillide B".Journal of Organic Chemistry 74.14(2009):5063-5066. |
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