| Investigation of the steam reforming of a series of model compounds derived from bio-oil for hydrogen production | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Hu X(胡勋); Lv GX(吕功煊)
| |
| 2009 | |
| Source Publication | Applied Catalysis B: Environmental
 |
| ISSN | 0926-3373 |
| Volume | 88Pages:376-385 |
| Abstract | In this study, steam reforming of acetic acid, ethylene glycol, acetone, ethyl acetate, m-xylene, and glucose, which were representative of themain components in bio-oil, were performed to investigate the feasibility of these feedstocks for hydrogen production. The effects of reaction temperature and steam to carbon ratios (S/C) on steam reforming as well as coke formation tendency of the bio-oil components in the presence and absence of steam were investigated in a detailed manner. Low reaction temperature and S/C led to low steam reforming efficiency, and consequently decomposition or degradation of the feedstocks dominated, resulting in large amounts of by-products. Increasing reaction temperature and S/C increased the steam reforming rates and the partial pressure of steam on catalyst surface, favoring conversion of the feedstocks and removal of the by-products. Coke formation rates of the feedstocks during the long-term experiments decreased in the following orders: glucose m-xylene> acetone > ethyl acetate > ethylene glycol > acetic acid. Decomposition or polymerization of the feedstocks to carbonaceous deposit was the main route for coke formation in glucose, m-xylene, and acetone reforming, while the large amounts of by-products such as ethylene, CO, or acetone were main sources of coke in the steam reforming of ethyl acetate, ethylene glycol, and acetic acid. |
| Keyword | Steam Reforming Hydrogen Bio-oil Coke Formation |
| Subject Area | 环境催化与清洁能源 |
| Funding Organization | the 973 Project of China (No. G 2003CB214503;2007CB613305) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 环境催化与清洁能源研究组 ; 环境催化与氢能源研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/529 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Lv GX(吕功煊) |
| Recommended Citation GB/T 7714 | Hu X,Lv GX. Investigation of the steam reforming of a series of model compounds derived from bio-oil for hydrogen production[J]. Applied Catalysis B: Environmental,2009,88:376-385. |
| APA | 胡勋,&吕功煊.(2009).Investigation of the steam reforming of a series of model compounds derived from bio-oil for hydrogen production.Applied Catalysis B: Environmental,88,376-385. |
| MLA | 胡勋,et al."Investigation of the steam reforming of a series of model compounds derived from bio-oil for hydrogen production".Applied Catalysis B: Environmental 88(2009):376-385. |
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| 12_Appl.Catal.B-Envi（663KB） | 开放获取 | License | View Application Full Text | |||
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