Catalytic Oxidation of Methane to C2-C4 Hydrocarbons over CeO2 Promoted W-Mn/SiO2 Catalysts at Higher Pressure | |
Department | OSSO国家重点实验室 |
Chou LJ(丑凌军); Cai YC(蔡迎春); Zhang B(张兵); Niu JZ(牛建中); Ji SF(季生福); Li SB(李树本); Li SB(李树本) | |
2004 | |
Source Publication | Journal of the Chinese Chemical Society |
ISSN | 0009-4536 |
Volume | 51Issue:1Pages:85-90 |
Abstract | CeO2-promoted Na-Mn-W/SiO2 catalyst has been studied for catalytic oxidation of methane in a microstainless-steel reactor at elevated pressure. The effect of operating conditions, such as GHSV, pressure and CH4/O2 ratio, has been investigated. 22.0% CH4 conversion with 73.8% C2-C4 selectivity (C2/C3/C4 =3.8/1.0/3.6) was obtained at 1003 K, 1.5 × 105 h-1 GHSV and 1.0 MPa. The results show: Elevated pressure disadvantages the catalytic oxidation of methane to C2-C4 hydrocarbons. Large amounts of C3 and C4 hydrocarbons are observed. The unfavorable effects of elevated pressure can be overcome by increasing GHSV; the reaction is strongly dependent on the operating conditions at elevated pressure, particularly dependent on GHSV and ratio of CH4/O2. Analyses by means of XRD, XPS and CO2-TPD show that CO2 produced from the reaction makes a weakly poisoning capacity of the catalyst; information of changeful valence on Ce and Mn was detected over the near-surface of the Ce-Na-W-Mn/SiO2 catalyst; the existence of Ce3+/Ce4+ and Mn2+/Mn3+ ion couple supported that the reaction over the catalyst followed the Redeal-Redox mechanism. Oxidative re-coupling of C2H6 and CH4 in gas phase or over surface of catalyst produces C3 or C4 hydrocarbons. |
Keyword | Ocm Elevated Pressure Ceo2-promoted Na-mn-w/sio2 Catalyst Useful Hydrocarbon |
Subject Area | 物理化学与绿色催化 |
Funding Organization | the “973” project of the Ministry of Science and Technology, P. R. China (Grant 1999022406) |
Indexed By | SCI |
If | 0.593 |
Language | 英语 |
Funding Project | 多相选择氧化研究组;大型仪器管理组 |
compositor | 第一作者单位 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/5033 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Li SB(李树本) |
Recommended Citation GB/T 7714 | Chou LJ,Cai YC,Zhang B,et al. Catalytic Oxidation of Methane to C2-C4 Hydrocarbons over CeO2 Promoted W-Mn/SiO2 Catalysts at Higher Pressure[J]. Journal of the Chinese Chemical Society,2004,51(1):85-90. |
APA | Chou LJ.,Cai YC.,Zhang B.,Niu JZ.,Ji SF.,...&李树本.(2004).Catalytic Oxidation of Methane to C2-C4 Hydrocarbons over CeO2 Promoted W-Mn/SiO2 Catalysts at Higher Pressure.Journal of the Chinese Chemical Society,51(1),85-90. |
MLA | Chou LJ,et al."Catalytic Oxidation of Methane to C2-C4 Hydrocarbons over CeO2 Promoted W-Mn/SiO2 Catalysts at Higher Pressure".Journal of the Chinese Chemical Society 51.1(2004):85-90. |
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