| Novel spiroketal-based diphosphite ligands for hydroformylation of terminal and internal olefins | |
| Department | OSSO国家重点实验室 |
Jia XF(贾肖飞)1,2; Wang Z(王正)2; Xia CG(夏春谷)1 ; Ding KL(丁奎岭)2; Xia CG(夏春谷); Ding KL(丁奎岭)
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| 2013 | |
| Source Publication | Catalysis Science and Technology
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| ISSN | 2044-4753 |
| Volume | 3Issue:8Pages:1901-1904 |
| Abstract | Spiroketal-based diphosphite ligands have been developed for the rhodium-catalyzed hydroformylation reaction. Under the optimized reaction conditions, a turnover number (TON) of up to 2.4 × 104 and a linear to branched ratio (l/b) of up to 93 were obtained in the hydroformylation of terminal olefins. The catalysts were also found to be effective in the isomerization–hydroformylation of some internal olefins. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c3cy00187c |
| Funding Organization | the National Natural Science Foundation of China (grant no. 21172237;21121062;21032009);the Major Basic Research Development Program of China (grant no. 2010CB833300);the Chinese Academy of Sciences;the Science and Technology Commission of Shanghai Municipality |
| Indexed By | SCI |
| If | 4.760 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4983 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Ding KL(丁奎岭) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| Recommended Citation GB/T 7714 | Jia XF,Wang Z,Xia CG,et al. Novel spiroketal-based diphosphite ligands for hydroformylation of terminal and internal olefins[J]. Catalysis Science and Technology,2013,3(8):1901-1904. |
| APA | Jia XF,Wang Z,Xia CG,Ding KL,夏春谷,&丁奎岭.(2013).Novel spiroketal-based diphosphite ligands for hydroformylation of terminal and internal olefins.Catalysis Science and Technology,3(8),1901-1904. |
| MLA | Jia XF,et al."Novel spiroketal-based diphosphite ligands for hydroformylation of terminal and internal olefins".Catalysis Science and Technology 3.8(2013):1901-1904. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Catal. Sci. Technol.（1040KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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