| One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2 | |
| Department | OSSO国家重点实验室 |
| Bai RX(白荣献)1; Zhang, Hongkun1; Mei FM(梅付名)1; Wang S(王庶)1; Li T(李涛)1; Gu YL(顾彦龙)1,2; Li GX(李光兴)1; Gu YL(顾彦龙); Li GX(李光兴) | |
| 2013 | |
| Source Publication | Green Chem.
 |
| ISSN | 1463-9262 |
| Volume | 15Issue:10Pages:2929-2934 |
| Abstract | The one-pot synthesis of glycidol from glycerol and dimethyl carbonate (DMC) was developed by using a solid base catalyst. A series of solid base catalysts have been investigated in this reaction. It was found that NaAlO2, a cheap and easily available raw material, was a highly efficient heterogeneous catalyst for the one-pot synthesis of glycidol, and it can be easily recovered and reused. Under the reaction conditions of a DMC–glycerol molar ratio of 2, catalyst–glycerol weight ratio of 3%, reaction time of 90 min, and temperature of 80–92 °C, the conversion of glycerol and the selectivity to glycidol reached 94.7% and 80.7%, respectively. Activity tests of the catalyst after exposure to the air showed that, to a certain extent, the NaAlO2 catalyst is tolerant to water and carbon dioxide, which makes the present system a practically interesting process for glycidol synthesis. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c3gc40855h |
| Funding Organization | National Natural Science Foundation of China (21173089);Chutian Scholar Program of the Hubei provincial government;the Cooperative Innovation Center of Catalysts Materials of Hubei Province |
| Indexed By | SCI |
| If | 6.852 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4947 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Gu YL(顾彦龙); Li GX(李光兴) |
| Affiliation | 1.Huazhong Univ Sci & Technol, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Large Format Battery Mat & Syst, Minist Educ,Sch Chem & Chem Engn, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Bai RX,Zhang, Hongkun,Mei FM,et al. One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2[J]. Green Chem.,2013,15(10):2929-2934. |
| APA | Bai RX.,Zhang, Hongkun.,Mei FM.,Wang S.,Li T.,...&李光兴.(2013).One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2.Green Chem.,15(10),2929-2934. |
| MLA | Bai RX,et al."One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2".Green Chem. 15.10(2013):2929-2934. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Green Chem., 2013,15（264KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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