| Sulfate Binding with a Tripodal Tris(4-pyridylurea) Receptor | |
| Department | OSSO国家重点实验室 |
Zhang R(张瑞)1; Zhang YL(张燕蕾)1; Wang JM(王佳敏)2 ; Ji, Liguo1; Huang XJ(黄晓卷)2; Wu B(吴彪)1; Wu B(吴彪)
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| 2013 | |
| Source Publication | Chinese Journal of Chemistry
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| ISSN | 1001-604X |
| Volume | 31Issue:5Pages:679-683 |
| Abstract | The tris(2-aminoethyl)amine (tren)-based tris(4-pyridylurea) receptor L has been synthesized and its anion binding properties were studied. The ligand forms a 2∶1 (host/guest) complex with MgSO4, [SO42−⊂L2], in which a sulfate ion is encapsulated by six urea groups from the two ligands through multiple hydrogen bonds. The metal ions do not coordinate to the pyridyl groups but exist as the hydrate [Mg(H2O)6]2＋ and interact with the [SO4⊂L2] capsules in the outer coordination sphere to form a three dimensional extended structure. The anion binding behavior of ligand L in solution was studied. |
| Keyword | Anion Binding Tripodal Tris(4-pyridylurea) Sulfate Capsule |
| DOI | 10.1002/cjoc.201300342 |
| Funding Organization | the National Natural Science Foundation of China (No. 21271149) |
| Indexed By | SCI |
| If | 1.040 |
| Language | 英语 |
| Funding Project | 日常管理与大型仪器组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4861 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Wu B(吴彪) |
| Affiliation | 1.NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Coll Chem & Mat Sci, Xian 710069, Shannxi, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang R,Zhang YL,Wang JM,et al. Sulfate Binding with a Tripodal Tris(4-pyridylurea) Receptor[J]. Chinese Journal of Chemistry,2013,31(5):679-683. |
| APA | Zhang R.,Zhang YL.,Wang JM.,Ji, Liguo.,Huang XJ.,...&吴彪.(2013).Sulfate Binding with a Tripodal Tris(4-pyridylurea) Receptor.Chinese Journal of Chemistry,31(5),679-683. |
| MLA | Zhang R,et al."Sulfate Binding with a Tripodal Tris(4-pyridylurea) Receptor".Chinese Journal of Chemistry 31.5(2013):679-683. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Chin. J. Chem. 2013,（1189KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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