| Oxidant controlled Pd-catalysed selective oxidation of primary alcohols | |
| Department | OSSO国家重点实验室 |
| Liu C(刘超)1; Tang S(唐山)1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
| 2013 | |
| Source Publication | Chemical Communications
 |
| ISSN | 1359-7345 |
| Volume | 49Issue:13Pages:1324-1326 |
| Abstract | The oxidant controlled palladium catalysed selective oxidation of primary alcohols to aldehydes or esters was investigated. The electronic properties of the benzylic alcohols and the structure of the oxidant are both important factors in controlling the selectivity between aldehydes and esters. A covalent benzyl ligand derived from BnCl provides g3 coordination to the Pd centre. This covalent ligand is the key to the selective oxidative esterification of primary alcohols. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c2cc38086b |
| Funding Organization | the 973 Program (2012CB725302);the National Natural Science Foundation of China (21025206;21272180);the China Postdoctoral Science Foundation funded project (2012M521458) |
| Indexed By | SCI |
| If | 6.718 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4855 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Liu C,Tang S,Lei AW,et al. Oxidant controlled Pd-catalysed selective oxidation of primary alcohols[J]. Chemical Communications,2013,49(13):1324-1326. |
| APA | Liu C,Tang S,Lei AW,&雷爱文.(2013).Oxidant controlled Pd-catalysed selective oxidation of primary alcohols.Chemical Communications,49(13),1324-1326. |
| MLA | Liu C,et al."Oxidant controlled Pd-catalysed selective oxidation of primary alcohols".Chemical Communications 49.13(2013):1324-1326. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Chem. Commun., 2013,（1183KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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