| pH-Responsive N-heterocyclic carbene copper(I) complexes: syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide | |
| Department | OSSO国家重点实验室 |
Wang WL(汪文龙)1,3; Zhang GD(张国栋)1,3; Lang R(郎睿)1,3 ; Xia CG(夏春谷)1; Li FW(李福伟)1,2; Li FW(李福伟)
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| 2013 | |
| Source Publication | Green Chemistry
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| ISSN | 1463-9262 |
| Volume | 15Issue:3Pages:635-640 |
| Abstract | A pH-controlled monophasic/biphasic switchable system has been developed as a green and novel strategy for homogeneous catalyst recycling, which has been successfully applied to the Cu-NHC-catalyzed carboxylation of organoboronic esters and benzoxazole with carbon dioxide. Additionally, the present strategy could also be extended to the Ag-NHC-catalyzed carboxylation of terminal alkyne. The tertiary amine-functionalized catalysts could be used for at least four times with a slight loss of activity. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c3gc36830k |
| Funding Organization | the National Natural Science Foundation of China (21002106;21133011);the Chinese Academy of Science |
| Indexed By | SCI |
| If | 6.852 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4799 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Li FW(李福伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China |
| Recommended Citation GB/T 7714 | Wang WL,Zhang GD,Lang R,et al. pH-Responsive N-heterocyclic carbene copper(I) complexes: syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide[J]. Green Chemistry,2013,15(3):635-640. |
| APA | Wang WL,Zhang GD,Lang R,Xia CG,Li FW,&李福伟.(2013).pH-Responsive N-heterocyclic carbene copper(I) complexes: syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide.Green Chemistry,15(3),635-640. |
| MLA | Wang WL,et al."pH-Responsive N-heterocyclic carbene copper(I) complexes: syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide".Green Chemistry 15.3(2013):635-640. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Green Chem., 2013, 1（881KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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