| 2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization | |
| Department | 羰基合成与选择氧化国家重点实验室 |
| Zhang M(张民); Zhang WJ(张文娟); 肖田鹏飞; Xiang JF(向俊峰); Hao X(郝项); Sun WH(孙文华) | |
| 2010 | |
| Source Publication | J. Mol. Catal. A: Chem.
 |
| ISSN | 1381-1169 |
| Volume | 320Pages:92-96 |
| Abstract | A series of 2-(1-aryliminopropyl)-1,10-phenanthrolines (L1–L7) and their corresponding iron(II) chlorides (Fe1–Fe7) are synthesized and characterized by elemental and spectroscopic analyses. The molecular structures of 2-[1-(2,6-diisopropy1phenylimino)propyl]-1,10-phenanthroline (L3) and {2-[1-(2,6-diethylphenylimino)propyl]-1,10-phenanthroline}·FeCl2 (Fe2) are determined by the single crystal X-ray diffraction. All iron complexes, activated with methylaluminoxane (MAO), exhibit high activities in ethylene oligomerization with high selectivity for -olefins produced. Compared with other 2-iminophenanthrolines, the title complexes show better thermal stability, and their oligomerization products are potentially more useful due to lower contents of butenes and waxes observed. |
| Keyword | Iron(Ii) Complexes 2-ethyl-ketimino-1 Ethylene Oligomerization 10-phenanthroline |
| Subject Area | 物理化学 |
| Funding Organization | NSFC no. 20674089 |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/476 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun WH(孙文华) |
| Recommended Citation GB/T 7714 | Zhang M,Zhang WJ,肖田鹏飞,et al. 2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization[J]. J. Mol. Catal. A: Chem.,2010,320:92-96. |
| APA | 张民,张文娟,肖田鹏飞,向俊峰,郝项,&孙文华.(2010).2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization.J. Mol. Catal. A: Chem.,320,92-96. |
| MLA | 张民,et al."2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization".J. Mol. Catal. A: Chem. 320(2010):92-96. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 35_J.Mol.Catal.A Che（664KB） | 开放获取 | License | View Application Full Text | |||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment