Activation of alkynes by an alpha-diimine-stabilized Al-Al-bonded compound: insertion into the Al-Al bond or cycloaddition to AlN2C2 rings | |
Department | OSSO国家重点实验室 |
Zhao YX(赵艳霞)1,3; Liu YY(刘艳艳)1; Lei YB(雷一波)2; Wu B(吴彪)2; Yang XJ(杨晓娟)1,2; Yang XJ(杨晓娟) | |
The second department | erc国家工程研究中心 |
2013 | |
Source Publication | Chemical Communications |
ISSN | 1359-7345 |
Volume | 49Issue:40Pages:4546-4548 |
Abstract | The reaction of dialumane, [L2-(THF)AlII–AlII(THF)L2-] (1, L = [(2,6-iPr2C6H3)NC(Me)]2), with the less reactive diphenylacetylene affords a new insertion product [L2-(THF)AlIII(PhCQCPh)2-AlIII(THF)L2-] (2). Reaction of 1 with phenylacetylene (or 4-ethynyltoluene), however, proceeds through cycloaddition of alkynes to the AlN2C2 rings to produce bis(bicyclic) products (3a and 3b). |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c3cc41756e |
Funding Organization | the National Natural Science Foundation of China (20972169;21273170) |
Indexed By | SCI |
If | 6.718 |
Language | 英语 |
Funding Project | 金属有机功能材料研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4720 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) 精细石油化工中间体国家工程研究中心(ERC) |
Corresponding Author | Yang XJ(杨晓娟) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Zhao YX,Liu YY,Lei YB,et al. Activation of alkynes by an alpha-diimine-stabilized Al-Al-bonded compound: insertion into the Al-Al bond or cycloaddition to AlN2C2 rings[J]. Chemical Communications,2013,49(40):4546-4548. |
APA | Zhao YX,Liu YY,Lei YB,Wu B,Yang XJ,&杨晓娟.(2013).Activation of alkynes by an alpha-diimine-stabilized Al-Al-bonded compound: insertion into the Al-Al bond or cycloaddition to AlN2C2 rings.Chemical Communications,49(40),4546-4548. |
MLA | Zhao YX,et al."Activation of alkynes by an alpha-diimine-stabilized Al-Al-bonded compound: insertion into the Al-Al bond or cycloaddition to AlN2C2 rings".Chemical Communications 49.40(2013):4546-4548. |
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Chem. Commun., 2013,(1354KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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