| Ionic liquids-based crosslinked copolymer sorbents for headspace solid-phase microextraction of polar alcohols | |
| Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Feng JJ(冯娟娟)1,2; Sun M(孙敏)3; Wang XS(王旭生)1 ; Liu X(刘霞)1; Jiang SX(蒋生祥)1; Jiang SX(蒋生祥)
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| 2012 | |
| Source Publication | Journal of Chromatography A
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| ISSN | 0021-9673 |
| Volume | 1245Pages:32-38 |
| Abstract | Halogen-based polymeric ionic liquid (PIL) fibers, which have proved efficient for solid-phase microextraction (SPME) of polar compounds, were with very limited fiber lifetimes. In this work, a novel crosslinked PIL sorbent with satisfactory stability and durability was prepared in situ via crosslinking polymerization processes on microstructured-silver coated stainless steel wire. 1,1′-(1,6-Hexanediyl)bis(1-vinylimidazolium) bibromide ionic liquid was synthesized and used as the crosslinking agent, with 1-vinyl-3-octylimidazolium bromide as monomer. Extraction properties of the fiber for polar alcohols in polar aqueous matrix were examined using headspace SPME (HS-SPME) coupled to gas chromatography-flame ionization detection (GC-FID). Under the optimized extraction and desorption conditions, the established method exhibited high extraction capacity. Wide linear ranges were obtained with correlation coefficients (R) ranging from 0.9947 to 0.9999. Limits of detection were in the range of 0.5–20 μg L−1. Compared with the non-crosslinked PIL fiber, the proposed crosslinked PIL fiber was with higher thermal stability and durability and longer lifetime. Four different liquor beverages were analyzed as real samples and good results were obtained. |
| Keyword | Crosslinking Copolymerization Polymeric Ionic Liquids Solid-phase Microextraction Alcohols Gas Chromatography |
| Subject Area | 分析化学与药物化学 |
| DOI | 10.1016/j.chroma.2012.05.026 |
| Funding Organization | the National Natural Science Foundation of China (Nos. 21175143;21975105) |
| Indexed By | SCI |
| If | 4.612 |
| Language | 英语 |
| Funding Project | 药物分离材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4608 |
| Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| Corresponding Author | Jiang SX(蒋生祥) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, CAS Key Lab Nat Med Gansu Prov, Key Lab Chem NW Plant Resources, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China |
| Recommended Citation GB/T 7714 | Feng JJ,Sun M,Wang XS,et al. Ionic liquids-based crosslinked copolymer sorbents for headspace solid-phase microextraction of polar alcohols[J]. Journal of Chromatography A,2012,1245:32-38. |
| APA | Feng JJ,Sun M,Wang XS,Liu X,Jiang SX,&蒋生祥.(2012).Ionic liquids-based crosslinked copolymer sorbents for headspace solid-phase microextraction of polar alcohols.Journal of Chromatography A,1245,32-38. |
| MLA | Feng JJ,et al."Ionic liquids-based crosslinked copolymer sorbents for headspace solid-phase microextraction of polar alcohols".Journal of Chromatography A 1245(2012):32-38. |
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| 冯娟娟-色谱A -ionic liqui（1117KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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