| Preparation of magnetic molecularly imprinted polymer for selective recognition of resveratrol in wine | |
| Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Chen FF(陈方方)1,2,3; Jie XY(解笑瑜)1,2,3; Shi YP(师彦平)1,2 ; Shi YP(师彦平)
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| 2013 | |
| Source Publication | Journal of Chromatography A
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| ISSN | 0021-9673 |
| Volume | 1300Pages:112-118 |
| Abstract | The magnetic molecularly imprinted polymers (MMIPs) for resveratrol were prepared by using sur-face molecular imprinting technique with a super paramagnetic core–shell nanoparticle as a supporter. Rhapontigenin, which is the analogues of resveratrol, was selected as dummy template molecules to avoidthe leakage of trace amount of resveratrol. Acrylamide and ethylene glycol dimethacrylate were chosenas functional monomers and cross-linker, respectively. The obtained MMIPs were characterized by usingscanning electron microscopy, Fourier transform infrared spectrum, X-ray diffraction and vibrating sam-ple magnetometer. High performance liquid chromatography was used to analyze the target analytes.The resulting MMIPs exhibited high saturation magnetization of 53.14 emu g−1leading to the fast sep-aration. The adsorption test showed that the MMIPs had high adsorption capacity for resveratrol andcontained homogeneous binding sites. The MMIPs were employed as adsorbent of solid phase extractionfor determination of resveratrol in real wine samples, and the recoveries of spiked samples ranged from79.3% to 90.6% with the limit of detection of 4.42 ng mL−1. The prepared MMIPs could be employed toselectively pre-concentrate and determine resveratrol from wine samples. |
| Keyword | Dummy Template Magnetic Molecularly Imprinted Polymers Resveratrol Wine Samples |
| Subject Area | 分析化学与药物化学 |
| DOI | 10.1016/j.chroma.2013.02.018 |
| Funding Organization | National Natural Science Founda-tion of China (Nos. 21075127;20875095) |
| Indexed By | SCI |
| If | 4.258 |
| Language | 英语 |
| Funding Project | 药物化学成分研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4589 |
| Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| Corresponding Author | Shi YP(师彦平) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Chen FF,Jie XY,Shi YP,et al. Preparation of magnetic molecularly imprinted polymer for selective recognition of resveratrol in wine[J]. Journal of Chromatography A,2013,1300:112-118. |
| APA | Chen FF,Jie XY,Shi YP,&师彦平.(2013).Preparation of magnetic molecularly imprinted polymer for selective recognition of resveratrol in wine.Journal of Chromatography A,1300,112-118. |
| MLA | Chen FF,et al."Preparation of magnetic molecularly imprinted polymer for selective recognition of resveratrol in wine".Journal of Chromatography A 1300(2013):112-118. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| JCA-2013(ChenFF).pdf（1211KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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