| Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene | |
| Department | OSSO国家重点实验室 |
Wang ZL(王仲来)1,2 ; Liu H(刘华)1,2; Chen L(陈龙)1; Chou LJ(丑凌军)1; Wang XL(王晓来)1; Wang XL(王晓来)
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| 2013 | |
| Source Publication | Journal of Materials Research
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| ISSN | 0884-2914 |
| Volume | 28Issue:10Pages:1326-1333 |
| Abstract | Carbon nanotubes (CNTs) supported Pd nanoparticle (NP) catalysts (Pd/CNTs) were prepared by a green and facile synthesis method based on hydrogen-bonding self-assembly. The size and loading of Pd NPs on catalysts were easily controlled by tuning both the relative amount of citrate to Pd salt in the solution and the relative amount of Pd NPs to CNTs. The size of Pd NPs on as-prepared catalysts can be tuned in the range of 3-6 nm, and Pd loading can be controlled in the range of 0-19 wt%. The catalysts were characterized by Brunauer-Emmett-Teller measurement, x-ray diffraction spectroscopy, and x-ray photoelectron spectroscopy. The performance of Pd/CNTs catalysts was evaluated in the hydrogenation of nitrobenzene. Compared with the catalysts prepared by the impregnation method or supported on conventional supports, Pd/CNTs catalysts show relatively higher activity and selectivity. The recyclability tests indicate that the Pd/CNTs catalysts can be used at least five times without significant loss in activity and selectivity. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1557/jmr.2013.101 |
| Indexed By | SCI |
| If | 1.815 |
| Language | 英语 |
| Funding Project | 多相选择氧化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4403 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Wang XL(王晓来) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Wang ZL,Liu H,Chen L,et al. Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene[J]. Journal of Materials Research,2013,28(10):1326-1333. |
| APA | Wang ZL,Liu H,Chen L,Chou LJ,Wang XL,&王晓来.(2013).Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene.Journal of Materials Research,28(10),1326-1333. |
| MLA | Wang ZL,et al."Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene".Journal of Materials Research 28.10(2013):1326-1333. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| green and facile syn（495KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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