LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts
DepartmentOSSO国家重点实验室
Wang ZL(王仲来)1,2; Chen L(陈龙)1; Luo X(雒旭)1,2; Zou GJ(邹国军)1; Gao RX(高润雄)1; Chou LJ(丑凌军)1; Wang XL(王晓来)1; Chou LJ(丑凌军); Wang XL(王晓来)
2013
Source PublicationAsian journal of chemistry
ISSN0970-7077
Volume25Issue:16Pages:9179-9184
AbstractOxidative coupling of methane (OCM) has been studied over a mixed catalyst constituted by Na2WO4-Mn/SiO2 (W) and BaCl2-TiO2-SnO2 (B). The effects of reaction temperature, gas hourly space velocity (GHSV) and CH4/O2 ratio on catalytic performance were systematic investigated. Compared with the single component counterpart, the results indicated that ethylene yield was significantly enhanced over the mixed catalysts. When the B/W ratio was controlled at 1/5 (v/v), the ethylene yield reached 22.2%, which was 7.1%, 2.1% higher than the single Na2WO4-Mn/SiO2, BaCl2-TiO2-SnO2 catalyst, respectively. Besides, the ethylene yield was higher than 20% over the mixed catalyst in wide reaction condition range.
KeywordOxidative Coupling Of Methane Mixed Catalyst Ethylene
Subject Area物理化学与绿色催化
Indexed BySCI
If0.355
Language英语
Funding Project多相选择氧化课题组
compositor第一作者单位
Citation statistics
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4402
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorChou LJ(丑凌军); Wang XL(王晓来)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China
Recommended Citation
GB/T 7714
Wang ZL,Chen L,Luo X,et al. Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts[J]. Asian journal of chemistry,2013,25(16):9179-9184.
APA Wang ZL.,Chen L.,Luo X.,Zou GJ.,Gao RX.,...&王晓来.(2013).Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts.Asian journal of chemistry,25(16),9179-9184.
MLA Wang ZL,et al."Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts".Asian journal of chemistry 25.16(2013):9179-9184.
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