Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts | |
Department | OSSO国家重点实验室 |
Wang ZL(王仲来)1,2; Chen L(陈龙)1; Luo X(雒旭)1,2; Zou GJ(邹国军)1; Gao RX(高润雄)1; Chou LJ(丑凌军)1; Wang XL(王晓来)1; Chou LJ(丑凌军); Wang XL(王晓来) | |
2013 | |
Source Publication | Asian journal of chemistry |
ISSN | 0970-7077 |
Volume | 25Issue:16Pages:9179-9184 |
Abstract | Oxidative coupling of methane (OCM) has been studied over a mixed catalyst constituted by Na2WO4-Mn/SiO2 (W) and BaCl2-TiO2-SnO2 (B). The effects of reaction temperature, gas hourly space velocity (GHSV) and CH4/O2 ratio on catalytic performance were systematic investigated. Compared with the single component counterpart, the results indicated that ethylene yield was significantly enhanced over the mixed catalysts. When the B/W ratio was controlled at 1/5 (v/v), the ethylene yield reached 22.2%, which was 7.1%, 2.1% higher than the single Na2WO4-Mn/SiO2, BaCl2-TiO2-SnO2 catalyst, respectively. Besides, the ethylene yield was higher than 20% over the mixed catalyst in wide reaction condition range. |
Keyword | Oxidative Coupling Of Methane Mixed Catalyst Ethylene |
Subject Area | 物理化学与绿色催化 |
Indexed By | SCI |
If | 0.355 |
Language | 英语 |
Funding Project | 多相选择氧化课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4402 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Chou LJ(丑凌军); Wang XL(王晓来) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China |
Recommended Citation GB/T 7714 | Wang ZL,Chen L,Luo X,et al. Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts[J]. Asian journal of chemistry,2013,25(16):9179-9184. |
APA | Wang ZL.,Chen L.,Luo X.,Zou GJ.,Gao RX.,...&王晓来.(2013).Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts.Asian journal of chemistry,25(16),9179-9184. |
MLA | Wang ZL,et al."Oxidative Coupling of Methane Over Mixed BaCl2-TiO2-SnO2 and Na2WO4-Mn/SiO2 Catalysts".Asian journal of chemistry 25.16(2013):9179-9184. |
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