In situ polymerization and mechanical, thermal properties of polyurethane/graphene oxide/epoxy nanocomposites | |
Department | 先进润滑与防护材料研究发展中心 |
Li YQ(李裕琪)1,2; Pan DY(潘笛远)4; Chen SB(陈守兵)1; Wang QH(王齐华)1; Pan GQ(潘广勤)3; Wang TM(王廷梅)1; Pan GQ(潘广勤); Wang TM(王廷梅) | |
The second department | 固体润滑国家重点实验室 |
2013 | |
Source Publication | Materials and Design |
ISSN | 0261-3069 |
Volume | 47Pages:850-856 |
Abstract | Significant reinforcement of polyurethane/epoxy (PU/EP) composites in situ synthesized on the graphene oxide nanosheets (GONS) is reported for the first time. Firstly, the PU prepolymer was in situ synthesized on the GONS. Then, the EP and a curing agent were added to prepare the PU/graphene oxide/EP (PU/GO/EP) nanocomposites. Morphologic study shows that, due to the formation of chemical bonding, the GONS was dispersed well in the PU/EP matrix and formed a strong interfacial interaction between the GONS and the matrix. With the incorporation of 0.066 wt% of GONS, the tensile modulus of PU/GO/EP nanocomposites increased from 218 MPa to 257 MPa, the tensile strength and elongation at the break of the PU/GO/EP nanocomposites increased by more than 52% and 103%, respectively. Additionally, the enhancing mechanism was tentatively proposed. The thermogravimetric analysis tests show that graphene oxide slightly changed the thermal stability of PU/GO/EP nanocomposites. It is hoped that our current work could provide an effective and promising method for preparing graphene-based polymer composites. |
Keyword | Nanocomposites Polymer Matrix Mechanical Properties Graphene Oxide |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.matdes.2012.12.077 |
Funding Organization | the National Science Foundation for Distinguished Young Scholars of China (Grant No. 51025517);the National Defense Basic Scientific Research Project (A1320110011) |
Indexed By | SCI |
If | 3.171 |
Language | 英语 |
Funding Project | 聚合物自润滑复合材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4395 |
Collection | 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 固体润滑国家重点实验室(LSL) |
Corresponding Author | Pan GQ(潘广勤); Wang TM(王廷梅) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.PetroChina, Lanzhou Petrochem Co, Res Inst, Lanzhou Inst Chem Ind, Lanzhou 730000, Peoples R China 4.Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China |
Recommended Citation GB/T 7714 | Li YQ,Pan DY,Chen SB,et al. In situ polymerization and mechanical, thermal properties of polyurethane/graphene oxide/epoxy nanocomposites[J]. Materials and Design,2013,47:850-856. |
APA | Li YQ.,Pan DY.,Chen SB.,Wang QH.,Pan GQ.,...&王廷梅.(2013).In situ polymerization and mechanical, thermal properties of polyurethane/graphene oxide/epoxy nanocomposites.Materials and Design,47,850-856. |
MLA | Li YQ,et al."In situ polymerization and mechanical, thermal properties of polyurethane/graphene oxide/epoxy nanocomposites".Materials and Design 47(2013):850-856. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
In situ polymerizati(1122KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment