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Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors
Department固体润滑国家重点实验室
Niu LY(牛棱渊)1,2; Li ZP(李章朋)1; Xu Y(许晔)1,2; Sun JF(孙金凤)1,2; Hong W(洪伟)1,2; Liu XH(刘晓红)1; Wang JQ(王金清)1; Yang SR(杨生荣)1; Wang JQ(王金清)
The second department先进润滑与防护材料研发中心
2013
Source PublicationACS Applied Materials & Interfaces
ISSN1944-8244
Volume5Issue:16Pages:8044-8052
AbstractThis study reports a simple synthesis of amorphous nickel tungstate (NiWO4) nanostructure and its application as a novel cathode material for supercapacitors. The effect of reaction temperature on the electrochemical properties of the NiWO4 electrode was studied, and results demonstrate that the material synthesized at 70 degrees C (NiW-70) has shown the highest specific capacitance of 586.2 F g-1 at 0.5 A g-1 in a three-electrode system. To achieve a high energy density, a NiW-70//activated carbon asymmetric supercapacitor is successfully assembled by use of NiW-70 and activated carbon as the cathode and anode, respectively, and then, its electrochemical performance is characterized by cyclic voltammetry and galvanostatic charge-discharge measurements. The results show that the assembled asymmetric supercapacitor can be cycled reversibly between 0 and 1.6 V with a high specific capacitance of 71.1 F g-1 at 0.25 A g-1, which can deliver a maximum energy density of 25.3 Wh kg-1 at a power density of 200 W kg-1. Furthermore, this asymmetric supercapacitor also presented an excellent, long cycle life along with 91.4% specific capacitance being retained after 5000 consecutive times of cycling.
KeywordAsymmetric Supercapacitor Nickel Tungstate Energy Storage Electrode Materials
Subject Area材料科学与物理化学
DOI10.1021/am402127u
Funding Organizationthe National Natural Science Foundation of China (Grant Nos. 51075384;51205385);the “Funds for Distinguished Young Scientists of Gansu Province”
Indexed BySCI
If5.900
Language英语
Funding Project聚合物摩擦学组;磨损与表面工程课题组
compositor第一作者单位
Citation statistics
Cited Times:289[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/4341
Collection固体润滑国家重点实验室(LSL)
中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
Corresponding AuthorWang JQ(王金清)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Niu LY,Li ZP,Xu Y,et al. Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors[J]. ACS Applied Materials & Interfaces,2013,5(16):8044-8052.
APA Niu LY.,Li ZP.,Xu Y.,Sun JF.,Hong W.,...&王金清.(2013).Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors.ACS Applied Materials & Interfaces,5(16),8044-8052.
MLA Niu LY,et al."Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors".ACS Applied Materials & Interfaces 5.16(2013):8044-8052.
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