Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors | |
Department | 固体润滑国家重点实验室 |
Niu LY(牛棱渊)1,2; Li ZP(李章朋)1; Xu Y(许晔)1,2; Sun JF(孙金凤)1,2; Hong W(洪伟)1,2; Liu XH(刘晓红)1; Wang JQ(王金清)1; Yang SR(杨生荣)1; Wang JQ(王金清) | |
The second department | 先进润滑与防护材料研发中心 |
2013 | |
Source Publication | ACS Applied Materials & Interfaces |
ISSN | 1944-8244 |
Volume | 5Issue:16Pages:8044-8052 |
Abstract | This study reports a simple synthesis of amorphous nickel tungstate (NiWO4) nanostructure and its application as a novel cathode material for supercapacitors. The effect of reaction temperature on the electrochemical properties of the NiWO4 electrode was studied, and results demonstrate that the material synthesized at 70 degrees C (NiW-70) has shown the highest specific capacitance of 586.2 F g-1 at 0.5 A g-1 in a three-electrode system. To achieve a high energy density, a NiW-70//activated carbon asymmetric supercapacitor is successfully assembled by use of NiW-70 and activated carbon as the cathode and anode, respectively, and then, its electrochemical performance is characterized by cyclic voltammetry and galvanostatic charge-discharge measurements. The results show that the assembled asymmetric supercapacitor can be cycled reversibly between 0 and 1.6 V with a high specific capacitance of 71.1 F g-1 at 0.25 A g-1, which can deliver a maximum energy density of 25.3 Wh kg-1 at a power density of 200 W kg-1. Furthermore, this asymmetric supercapacitor also presented an excellent, long cycle life along with 91.4% specific capacitance being retained after 5000 consecutive times of cycling. |
Keyword | Asymmetric Supercapacitor Nickel Tungstate Energy Storage Electrode Materials |
Subject Area | 材料科学与物理化学 |
DOI | 10.1021/am402127u |
Funding Organization | the National Natural Science Foundation of China (Grant Nos. 51075384;51205385);the “Funds for Distinguished Young Scientists of Gansu Province” |
Indexed By | SCI |
If | 5.900 |
Language | 英语 |
Funding Project | 聚合物摩擦学组;磨损与表面工程课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/4341 |
Collection | 固体润滑国家重点实验室(LSL) 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 |
Corresponding Author | Wang JQ(王金清) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100080, Peoples R China |
Recommended Citation GB/T 7714 | Niu LY,Li ZP,Xu Y,et al. Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors[J]. ACS Applied Materials & Interfaces,2013,5(16):8044-8052. |
APA | Niu LY.,Li ZP.,Xu Y.,Sun JF.,Hong W.,...&王金清.(2013).Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors.ACS Applied Materials & Interfaces,5(16),8044-8052. |
MLA | Niu LY,et al."Simple Synthesis of Amorphous NiWO4 Nanostructure and Its Application as a Novel Cathode Material for Asymmetric Supercapacitors".ACS Applied Materials & Interfaces 5.16(2013):8044-8052. |
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2. Niu LY (ACS appl(1425KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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