| Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids | |
| Department | OSSO国家重点实验室 |
Wu L(吴丽)1,2 ; Li Z(李臻)1; Wang F(王芳)1; Lei M(雷敏)1,2; Chen J(陈静)1; Li Z(李臻)
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| 2013 | |
| Source Publication | Journal of Molecular Catalysis A: Chemical
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| ISSN | 1381-1169 |
| Volume | 379Pages:86-93 |
| Abstract | Several Brönsted acidic ionic liquids (BAILs) were synthesized and used as catalysts for the cyclotrimeriza-tion of propanal. The acidity of different BAILs was explored and a preliminarily study of the relationshipbetween catalytic activity and acidity was performed. The kinetics for the BAILs-catalyzed cyclotrimer-ization of propanal was studied systemically to determine the kinetic model and the kinetic parametersby taking [BSTMG][HSO4] as the representative catalyst. The effects of various parameters such as cat-alyst loading, reaction temperature on the kinetics were examined in detail. Besides, the structures ofthree representative BAILs and the interactions between propanal molecule and ionic pairs of BAILs werestudied by means of quantum chemistry calculations. |
| Keyword | Bronsted Acidic Ionic Liquids Cyclotrimerization Kinetics Study Quantum Chemistry Calculations |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.molcata.2013.07.021 |
| Funding Organization | the National Natural Science Foundation of China (No. 21133011);National Basic Research Program of China (973 Program) (No. 2011CB201404) |
| Indexed By | SCI |
| If | 3.679 |
| Language | 英语 |
| Funding Project | 分子催化与技术课题组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4254 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Li Z(李臻) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Wu L,Li Z,Wang F,et al. Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids[J]. Journal of Molecular Catalysis A: Chemical,2013,379:86-93. |
| APA | Wu L,Li Z,Wang F,Lei M,Chen J,&李臻.(2013).Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids.Journal of Molecular Catalysis A: Chemical,379,86-93. |
| MLA | Wu L,et al."Kinetics and quantum chemical study for cyclotrimerization of propanal catalyzed by Bronsted acidic ionic liquids".Journal of Molecular Catalysis A: Chemical 379(2013):86-93. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2013年——Kinetics and （1381KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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