| Butene catalytic cracking to ethylene and propylene on fluorinated ZSM-5-based catalyst | |
| Department | ERC国家工程研究中心 |
Tang ZC(唐志诚)1 ; Zhang P(张朋)1; Han WL(韩维亮)1; Lu GX(吕功煊)1; Lu JY(陆江银)2,3; Tang ZC(唐志诚)
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| The second department | osso国家重点实验室 |
| 2013 | |
| Source Publication | Reaction Kinetics, Mechanisms and Catalysis
 |
| ISSN | 1878-5190 |
| Volume | 108Issue:1Pages:231-239 |
| Abstract | In this paper, fluorine-containing ZSM-5 catalysts were first prepared and applied for butene catalytic cracking. Fluorinated ZSM-5 was obtained by treating the ZSM-5 zeolite with NH4F solutions at 85 C. XRD showed that the intrinsic mordenite framework inverted structure of ZSM-5 zeolite was preserved and the corresponding crystallinity remained unchanged. The N2 adsorption/desorption measure indicated the generation of a number of new micropores. The experiment of butene catalytic cracking showed that catalytic performances can be greatly improved after fluorination treatment. The highest yield of ethylene plus propylene was obtained when the treated concentration of NH4F solution is 0.1 M. |
| Keyword | Fluorinated Treatment Catalytic Cracking Ethylene And Propylene Micropore Zsm-5 Zeolite |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1007/s11144-012-0512-7 |
| Funding Organization | West Light Foundation of The Chinese Academy of Sciences;Science and Technique Program of Lanzhou City, Science-Technology Foundation for Middle-Aged and Young Scientist of Gansu Province;Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, Xinjiang University (XJDX0908-2011-03) |
| Indexed By | SCI |
| If | 0.983 |
| Language | 英语 |
| Funding Project | 工业催化课题组;环境催化与氢能源研究组;环境催化与清洁能源研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4232 |
| Collection | 精细石油化工中间体国家工程研究中心（ERC） 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Tang ZC(唐志诚) |
| Affiliation | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Xinjiang Univ, Key Lab Oil & Gas Fine Chem, Minist Educ, Urumqi 830046, Xinjiang, Peoples R China 3.Xinjiang Univ, Xinjiang Uyghur Autonomous Reg, Urumqi 830046, Xinjiang, Peoples R China |
| Recommended Citation GB/T 7714 | Tang ZC,Zhang P,Han WL,et al. Butene catalytic cracking to ethylene and propylene on fluorinated ZSM-5-based catalyst[J]. Reaction Kinetics, Mechanisms and Catalysis,2013,108(1):231-239. |
| APA | Tang ZC,Zhang P,Han WL,Lu GX,Lu JY,&唐志诚.(2013).Butene catalytic cracking to ethylene and propylene on fluorinated ZSM-5-based catalyst.Reaction Kinetics, Mechanisms and Catalysis,108(1),231-239. |
| MLA | Tang ZC,et al."Butene catalytic cracking to ethylene and propylene on fluorinated ZSM-5-based catalyst".Reaction Kinetics, Mechanisms and Catalysis 108.1(2013):231-239. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Butene catalytic cra（233KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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