| Platinum/scandium-cocatalyzed cascade cyclization and ring-opening reaction of tertiary amines with substituted salicylaldehydes to synthesize 3-(aminoalkyl)coumarins | |
| Department | 固体润滑国家重点实验室 |
| Xia XF(夏晓峰); Shu XZ(舒兴中); Ji KG(纪克攻); Ali Shaukat; Liu XY(刘雪原); Liang YM(梁永民) | |
| 2011 | |
| Source Publication | J. Org. Chem.
 |
| ISSN | 0022-3263 |
| Volume | 76Pages:342-345 |
| Abstract | The synthesis of 3-(aminoalkyl)coumarins starting with a platinum/scandium-cocatalyzed oxidative dehydrogena- tion of R,β-C(sp3 )-H bonds of tertiary amines in the presence of ambient oxygen followed by reactions with substituted salicylaldehydes is revealed. The in situ formed enamines reacted with various salicylaldehydes, which resulted in the development of a one-pot synthetic protocol involving aldol reaction, cyclization, and then ring-opening. |
| Subject Area | 材料科学与物理化学 |
| Funding Organization | the National Science Foundation (NSF-20732002,NSF-20090443,NSF-20872052,NSF-21072080) |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3962 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Liang YM(梁永民) |
| Recommended Citation GB/T 7714 | Xia XF,Shu XZ,Ji KG,et al. Platinum/scandium-cocatalyzed cascade cyclization and ring-opening reaction of tertiary amines with substituted salicylaldehydes to synthesize 3-(aminoalkyl)coumarins[J]. J. Org. Chem.,2011,76:342-345. |
| APA | 夏晓峰,舒兴中,纪克攻,Ali Shaukat,刘雪原,&梁永民.(2011).Platinum/scandium-cocatalyzed cascade cyclization and ring-opening reaction of tertiary amines with substituted salicylaldehydes to synthesize 3-(aminoalkyl)coumarins.J. Org. Chem.,76,342-345. |
| MLA | 夏晓峰,et al."Platinum/scandium-cocatalyzed cascade cyclization and ring-opening reaction of tertiary amines with substituted salicylaldehydes to synthesize 3-(aminoalkyl)coumarins".J. Org. Chem. 76(2011):342-345. |
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| File Name/Size | DocType | Version | Access | License | ||
| 2011342-345.PDF（775KB） | 开放获取 | CC BY-NC-SA | View Application Full Text | |||
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