| Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates | |
| Department | 羰基合成与选择氧化国家重点实验室 |
| Huang W(黄伟); Zhang WJ(张文娟); Liu SF(刘绍峰); Liang TL(梁同玲); Sun WH(孙文华) | |
| 2011 | |
| Source Publication | J. Polym. Sci., Part A: Polym. Chem.
 |
| ISSN | 1099-0518 |
| Volume | 49Issue:8Pages:1887-1894 |
| Abstract | A series of trichlorotitanium complexes containing 2-(1-(arylimino)propyl)quinolin-8-olates was synthesized by stoichiometric reaction of titanium tetrachloride with the corresponding potassium 2-(1-(arylimino)propyl)quinolin-8-olates and was fully characterized by elemental analysis, nuclear magnetic resonance spectroscopy, and by single-crystal X-ray diffraction study of representative complexes. All titanium complexes, when activated with methylaluminoxane, exhibited high catalytic activity toward ethylene polymerization [up to 1.15 106 g mol 1(Ti) h 1] and ethylene/a-olefin copolymerization [up to 1.54 106 g mol 1 (Ti) h 1]. The incorporation of comonomer was confirmed to amount up to 2.82 mol % of 1-hexene or 1.94 mol % of 1-octene, respectively. VC 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 1887– 1894, 2011 |
| Keyword | Addition Polymerization 2-(1-(Arylimino)Propyl)Quinolin-8-olates Copolymerization Ethylene Homopolymerization Metal-organic Catalysts/organometallic Catalysts Polyethylene (Pe) Trichlorotitanium Pro-catalyst |
| Subject Area | 物理化学 |
| Funding Organization | Natural Science Foundation of China (NSFC) (nos. 20874105;20904059);the Ministry of Science and Technology (MOST) 863 Program (no. 2009AA034601) |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/389 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun WH(孙文华) |
| Recommended Citation GB/T 7714 | Huang W,Zhang WJ,Liu SF,et al. Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates[J]. J. Polym. Sci., Part A: Polym. Chem.,2011,49(8):1887-1894. |
| APA | 黄伟,张文娟,刘绍峰,梁同玲,&孙文华.(2011).Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates.J. Polym. Sci., Part A: Polym. Chem.,49(8),1887-1894. |
| MLA | 黄伟,et al."Synthesis, Characterization, and Ethylene (Co)Polymerization Behavior of Trichlorotitanium 2-(1-(Arylimino)propyl)quinolin-8-olates".J. Polym. Sci., Part A: Polym. Chem. 49.8(2011):1887-1894. |
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| 45-Journal of Polyme（244KB） | 开放获取 | License | View Application Full Text | |||
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