| Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde | |
| Department | OSSO国家重点实验室 |
Song HY(宋河远) ; Li Z(李臻); Chen J(陈静); Xia CG(夏春谷); Li Z(李臻); Chen J(陈静)
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| 2012 | |
| Source Publication | Catalysis Letters
 |
| ISSN | 1011-372X |
| Volume | 142Issue:1Pages:81-86 |
| Abstract | Methyl glycolate (MG), as a precursor to ethylene glycol (EG), was synthesized by an efficient and eco-friendly procedure of one-pot, two-step, sequential reaction, including carbonylation and esterification from HCHO with Brönsted acidic ionic liquids (BAILs) as catalysts. MG was obtained in high yield under mild conditions. In addition, the catalyst could be recycled eight times after separating the unreacted materials and products from the reaction system by distillation under vacuum and no significant decrease in catalytic activity was observed. |
| Keyword | Formaldehyde Carbonylation Methyl Glycolate Ethylene Glycol Ionic Liquids |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1007/s10562-011-0708-x |
| Funding Organization | National Basic Research Program of China (973 Program) 2011CB201404;the Key Project of the National Twelfth-Five Year Research Program of China 2011BAE17B00 |
| Indexed By | SCI |
| If | 2.244 |
| Language | 英语 |
| Funding Project | 分子催化与技术课题组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3890 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Li Z(李臻); Chen J(陈静) |
| Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Song HY,Li Z,Chen J,et al. Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde[J]. Catalysis Letters,2012,142(1):81-86. |
| APA | Song HY,Li Z,Chen J,Xia CG,李臻,&陈静.(2012).Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde.Catalysis Letters,142(1),81-86. |
| MLA | Song HY,et al."Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde".Catalysis Letters 142.1(2012):81-86. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| B47.Catal Lett (2012（328KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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