| Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines | |
| Department | 羰基合成与选择氧化国家重点实验室 |
| Song SJ(宋盛菊); Zhao WZ(赵炜珍); Wang L(王林); Carl Redshaw; Wang FS(王佛松); Sun WH(孙文华) | |
| 2011 | |
| Source Publication | J. Organomet. Chem.
 |
| ISSN | 0022-328X |
| Volume | 696Pages:3029-3035 |
| Abstract | A series of 2-(1-aryliminoethylidene)quinolines (L) were synthesized and used as bidentate N^N ligands in coordinating with metal (cobalt and iron) chlorides to form complexes of the type LMCl2, cobalt(II) (Co1eCo5) and iron(II) (Fe1eFe5). All organic compounds and metal complexes were fully characterized, and the molecular structures of the representative complexes Co3$DMF and Fe4$DMF were confirmed as distorted bipyramidal geometry at the metal by single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) under 10 atm ethylene, all complexes showed high activities in ethylene dimerization with activities of up to 1.82 106 g mol 1 (Co) h 1 and 5.89 105 g mol 1 (Fe) h 1, respectively. |
| Keyword | Ethylene Dimerization 2-(1-aryliminoethylidene)Quinoline Cobalt Iron |
| Subject Area | 物理化学 |
| Funding Organization | the MOST 863 program No. 2009AA033601 |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/388 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun WH(孙文华) |
| Recommended Citation GB/T 7714 | Song SJ,Zhao WZ,Wang L,et al. Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines[J]. J. Organomet. Chem.,2011,696:3029-3035. |
| APA | 宋盛菊,赵炜珍,王林,Carl Redshaw,王佛松,&孙文华.(2011).Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines.J. Organomet. Chem.,696,3029-3035. |
| MLA | 宋盛菊,et al."Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines".J. Organomet. Chem. 696(2011):3029-3035. |
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