| Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties | |
| Department | OSSO国家重点实验室 |
Zhao HH(赵华华)1,2 ; Song HL(宋焕玲)1; Chou LJ(丑凌军)1; Chou LJ(丑凌军)
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| 2012 | |
| Source Publication | Inorganic Chemistry Communications
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| ISSN | 1387-7003 |
| Volume | 15Pages:261-265 |
| Abstract | Nickel nanoparticles (2–6 nm) were successfully deposited on MOF-5 (Zn4O(BDC)3, BDC = 1,4-benzenedicarboxylate) by a facile wet impregnation strategy to prepare Ni@MOF-5 employing Ni(acac)2 (acac = acetylacetonate) as the precursor in absolute ethanol solvent owing to the sensitivity to the moisture of MOF-5. Ni@MOF-5 exhibited excellent catalytic activity for hydrogenation of C = C bond using crotonaldehyde as a probe molecule under mild reaction conditions (conversion > 90.0%, selectivity > 98.0%, 2.0 MPa, 100 °C, 40 min). In addition, the catalyst could be reused and the structure of MOF-5 framework was still maintained. Therefore, MOF-5 promised a novel candidate of support for hydrogenation catalyst. |
| Keyword | Wet Impregnation Strategy Ni@mof-5 Crotonaldehyde Hydrogenation |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.inoche.2011.10.040 |
| Funding Organization | the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China |
| Indexed By | SCI |
| If | 2.016 |
| Language | 英语 |
| Funding Project | 多相催化研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3889 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Chou LJ(丑凌军) |
| Affiliation | 1.Chinese Acad Sci, Stare Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao HH,Song HL,Chou LJ,et al. Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties[J]. Inorganic Chemistry Communications,2012,15:261-265. |
| APA | Zhao HH,Song HL,Chou LJ,&丑凌军.(2012).Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties.Inorganic Chemistry Communications,15,261-265. |
| MLA | Zhao HH,et al."Nickel nanoparticles supported on MOF-5: Synthesis and catalytic hydrogenation properties".Inorganic Chemistry Communications 15(2012):261-265. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| B46.Inorganic Chemis（511KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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