| Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes | |
| Department | ERC国家工程研究中心 |
Cui FJ(崔凤娟)1,2; Li SG(李少光)1,2; Jia CD(贾传东)1,2; Mathieson, Jennifer S.3; Cronin, Leroy3; Yang XJ(杨晓娟)1 ; Wu B(吴彪)1; Wu B(吴彪)
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| The second department | osso国家重点实验室 |
| 2012 | |
| Source Publication | Inorganic Chemistry
 |
| ISSN | 0020-1669 |
| Volume | 51Issue:1Pages:179-187 |
| Abstract | A series of dinuclear triple-stranded complexes, [Fe2L3⊃X]X6 [X = BF4– (1), ClO4– (2)], [Fe2L3⊃SO4]2(SO4)5 (3), [Fe2L3⊃Br](BPh4)6 (4), Fe2L3(NO3)Br6 (5), and [Cu2L3⊃NO3](NO3)6 (6), which incorporate a central cavity to encapsulate different anions, have been synthesized via the self-assembly of iron(II) or copper(II) salts with the N,N′-bis[5-(2,2′-bipyridyl)methyl]imidazolium bromide (LBr) ligand. X-ray crystallographic studies (for 1–4 and 6) and elemental analyses confirmed the cagelike triple-stranded structure. The anionic guest is bound in the cage and shows remarkable influence on the outcome of the self-assembly process with regard to the configuration at the metal centers. The mesocates (with different configurations at the two metal centers) have formed in the presence of large tetrahedral anions, while helicates (with the same configuration at both metal centers) were obtained when using the relatively smaller spherical or trigonal-planar anions Br– or NO3–. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/ic201417y |
| Funding Organization | the National Natural Science Foundation of China (Grant 20872149);WestCHEM and the EPSRC for funding |
| Indexed By | SCI |
| If | 4.593 |
| Language | 英语 |
| Funding Project | 金属有机功能材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3830 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Wu B(吴彪) |
| Affiliation | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland |
| Recommended Citation GB/T 7714 | Cui FJ,Li SG,Jia CD,et al. Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes[J]. Inorganic Chemistry,2012,51(1):179-187. |
| APA | Cui FJ.,Li SG.,Jia CD.,Mathieson, Jennifer S..,Cronin, Leroy.,...&吴彪.(2012).Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes.Inorganic Chemistry,51(1),179-187. |
| MLA | Cui FJ,et al."Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes".Inorganic Chemistry 51.1(2012):179-187. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 51.Inorg. Chem., 201（521KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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