| Photocatalytic hydrogen evolution over Pt/Cd0.5Zn0.5S from saltwater using glucose as electron donor: An investigation of the influence of electrolyte NaCl | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Li YX(李越湘); Gao D(高丹); Peng SQ(彭绍琴); Lv GX(吕功煊) ; Li SB(李树本)
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| 2011 | |
| Source Publication | Int. J. Hydrog. Energy
 |
| ISSN | 0360-3199 |
| Volume | 36Pages:4291-4297 |
| Abstract | Surface property of Cd0.5Zn0.5S in basic aqueous solution was characterized by X-ray photoelectron spectroscope (XPS). The surface S species at Cd0.5Zn0.5S under basic condition is substituted by O species. The surface adsorption performance of glucose and NaCl was characterized by adsorption experiment and electrophoretic analysis. Glucose is adsorbed on Cd0.5Zn0.5S via two modes. Naþ can be also adsorbed on Cd0.5Zn0.5S. The effect of electrolyte NaCl on photocatalytic hydrogen evolution over Pt/Cd0.5Zn0.5S using glucose as an electron donor has been investigated under visible light irradiation. NaCl can promote markedly the photocatalytic hydrogen evolution, which is very important to practical application. The photocatalytic activity for hydrogen evolution from 3.0 mol L 1 NaCl saltwater increases by 77% compared to that from pure water. A possible mechanism was discussed. |
| Keyword | Photocatalysis Hydrogen Evolution Sodium Chloride Glucose Cd0.5zn0.5s |
| Subject Area | 物理化学 |
| Funding Organization | the National Basic Research Program of China (2009CB220003);the National Nature Science Foundation of China (No.20763006);Specialized Research Fund for the Doctoral Program of Higher Education of China (20060403006);Research Fund of Education Ministry of Jiangxi, China(GJJ09041) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 环境催化与氢能研究组 ; 环境催化与氢能源研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/382 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Li YX(李越湘) |
| Recommended Citation GB/T 7714 | Li YX,Gao D,Peng SQ,et al. Photocatalytic hydrogen evolution over Pt/Cd0.5Zn0.5S from saltwater using glucose as electron donor: An investigation of the influence of electrolyte NaCl[J]. Int. J. Hydrog. Energy,2011,36:4291-4297. |
| APA | 李越湘,高丹,彭绍琴,吕功煊,&李树本.(2011).Photocatalytic hydrogen evolution over Pt/Cd0.5Zn0.5S from saltwater using glucose as electron donor: An investigation of the influence of electrolyte NaCl.Int. J. Hydrog. Energy,36,4291-4297. |
| MLA | 李越湘,et al."Photocatalytic hydrogen evolution over Pt/Cd0.5Zn0.5S from saltwater using glucose as electron donor: An investigation of the influence of electrolyte NaCl".Int. J. Hydrog. Energy 36(2011):4291-4297. |
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