| 2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization | |
| Department | 羰基合成与选择氧化国家重点实验室 |
| Song SJ(宋盛菊); Gao R(高榕); Zhang M(张民); Li Y(李言); Wang FS(王佛松); Sun WH(孙文华) | |
| 2011 | |
| Source Publication | Inorg. Chim. Acta
 |
| ISSN | 0020-1693 |
| Volume | 376Pages:373-380 |
| Abstract | A series of 2-(2-benzothiazolyl)-6-(1-(arylimino)ethyl)pyridines and their metal (Fe or Co) complexes were prepared. All organic compounds were fully characterized by NMR, FT-IR spectra and elemental analysis, and all metal complexes were identified by FT-IR spectroscopic and elemental analysis. The molecular structures of representative metal complexes were confirmed by single-crystal X-ray diffraction and displayed the distorted trigonal bipyramid geometry. Upon activation with modified methylaluminoxane (MMAO), the iron pro-catalysts showed good catalytic activities up to the range of 107 g mol 1(Fe) h 1 in ethylene reactivity with the high selectivity for the vinyl-type products of both oligomers and polyethylene waxes; whereas the cobalt pro-catalysts showed moderate activities towards ethylene oligomerization. The correlations between metal complexes and their catalytic activities and products were investigated in detail under various reaction parameters and discussed. |
| Keyword | 2-b-benzothiazolyl-6-iminopyridine Iron Cobalt Oligomerization Polymerization |
| Subject Area | 物理化学 |
| Funding Organization | NSFC No. 20874105;MOST 863 program No. 2009AA033601 |
| Indexed By | SCI |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/380 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun WH(孙文华) |
| Recommended Citation GB/T 7714 | Song SJ,Gao R,Zhang M,et al. 2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization[J]. Inorg. Chim. Acta,2011,376:373-380. |
| APA | 宋盛菊,高榕,张民,李言,王佛松,&孙文华.(2011).2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization.Inorg. Chim. Acta,376,373-380. |
| MLA | 宋盛菊,et al."2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization".Inorg. Chim. Acta 376(2011):373-380. |
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