Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites | |
Department | OSSO国家重点实验室 |
Hou CD(侯超东)1,2; Ren YL(任运来)2; Lang R(郎睿)1; Hu XX(胡霄雪)1; Xia CG(夏春谷)1; Li FW(李福伟)1; Li FW(李福伟) | |
2012 | |
Source Publication | Chemical Communications |
ISSN | 1359-7345 |
Volume | 48Issue:42Pages:5181-5183 |
Abstract | The first Pd-catalyzed direct phosphonation of azoles with dialkyl phosphites has been achieved without addition of base or acid. This method involves the oxidative cleavage of C-H and P(O)-H bonds and represents an atom-efficiency alternative to the classical phosphonation of Ar-X. A Pd-II/Pd-IV mechanism has been studied and proposed. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c2cc30429e |
Funding Organization | the Chinese Academy of Sciences and the National Natural Science Foundation of China (21002106;21133011) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 均相催化研究组;日常管理与大型仪器组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/3798 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Li FW(李福伟) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Peoples R China |
Recommended Citation GB/T 7714 | Hou CD,Ren YL,Lang R,et al. Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites[J]. Chemical Communications,2012,48(42):5181-5183. |
APA | Hou CD.,Ren YL.,Lang R.,Hu XX.,Xia CG.,...&李福伟.(2012).Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites.Chemical Communications,48(42),5181-5183. |
MLA | Hou CD,et al."Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites".Chemical Communications 48.42(2012):5181-5183. |
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17.Chem. Commun., 20(671KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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