| "Push effect" of sulfur coordination: promoting the breaking of C(sp(2))-I bond by pincer thioimido-Pd(II) complexes | |
| Department | OSSO国家重点实验室 |
| Liu J(刘婧)1; Deng Y(邓轶)1; Lin CT(林才涛)1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
| 2012 | |
| Source Publication | Chemical Science
 |
| ISSN | 2041-6520 |
| Volume | 3Issue:4Pages:1211-1214 |
| Abstract | Aryl-iodo bond cleavage by pincer thioimido-Pd(II) complex was demonstrated by in situ IR and X-ray analysis. Stoichiometric reactions indicated the crucial role of substrate sulfur coordination to the Pd centre. Possible mechanisms were proposed and catalytic reaction was developed. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c2sc00888b |
| Funding Organization | the National Natural Science Foundation of China (21025206;20832003;20972118);the “973” Project from the MOST of China (2011CB808600);“the Fundamental Research Funds for the Central Universities”, Program for New Century Excellent Talents in University (NCET);the Program for Changjiang Scholars and Innovative Research Team in University (IRT1030);Academic Award for Excellent Ph.D. Candidates Funded by Ministry of Education of China |
| Indexed By | SCI |
| If | 8.314 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3792 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Liu J,Deng Y,Lin CT,et al. "Push effect" of sulfur coordination: promoting the breaking of C(sp(2))-I bond by pincer thioimido-Pd(II) complexes[J]. Chemical Science,2012,3(4):1211-1214. |
| APA | Liu J,Deng Y,Lin CT,Lei AW,&雷爱文.(2012)."Push effect" of sulfur coordination: promoting the breaking of C(sp(2))-I bond by pincer thioimido-Pd(II) complexes.Chemical Science,3(4),1211-1214. |
| MLA | Liu J,et al.""Push effect" of sulfur coordination: promoting the breaking of C(sp(2))-I bond by pincer thioimido-Pd(II) complexes".Chemical Science 3.4(2012):1211-1214. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 12.Chem. Sci., 2012,（322KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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