| Palladium-Catalyzed Oxidative Carbonylation of Benzylic C-H Bonds via Nondirected C(sp(3))-H Activation | |
| Department | OSSO国家重点实验室 |
Jie P(解攀) ; Xie YJ(谢银君); Qian B(钱波); Zhou H(周晗); Xia CG(夏春谷); Huang HM(黄汉民); Huang HM(黄汉民)
| |
| 2012 | |
| Source Publication | Journal of the American Chemical Society
 |
| ISSN | 0002-7863 |
| Volume | 134Issue:24Pages:9902-9905 |
| Abstract | A new strategy for generating benzylpalladium reactive species from toluenes via nondirected C(sp3)−H activation has been developed. This led to construction of an efficient Pd-catalyzed reaction protocol for the oxidative carboxylation of benzylic C−H bonds to form substituted 2-phenylacetic acid esters and derivatives from inexpensive, commercially available starting materials. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/ja3036459 |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21172226;21133011) |
| Indexed By | SCI |
| If | 10.677 |
| Language | 英语 |
| Funding Project | 有机功能材料研究组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3789 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Jie P,Xie YJ,Qian B,et al. Palladium-Catalyzed Oxidative Carbonylation of Benzylic C-H Bonds via Nondirected C(sp(3))-H Activation[J]. Journal of the American Chemical Society,2012,134(24):9902-9905. |
| APA | Jie P.,Xie YJ.,Qian B.,Zhou H.,Xia CG.,...&黄汉民.(2012).Palladium-Catalyzed Oxidative Carbonylation of Benzylic C-H Bonds via Nondirected C(sp(3))-H Activation.Journal of the American Chemical Society,134(24),9902-9905. |
| MLA | Jie P,et al."Palladium-Catalyzed Oxidative Carbonylation of Benzylic C-H Bonds via Nondirected C(sp(3))-H Activation".Journal of the American Chemical Society 134.24(2012):9902-9905. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 9.J. Am. Chem. Soc.,（249KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment