| Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids | |
| Department | 绿色化学与催化研发中心 |
Shi F(石峰) ; He YD(何昱德); Li DM(李冬梅); Ma YB(马昱博); Zhang QH(张庆华); Deng YQ(邓友全)
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| 2006 | |
| Source Publication | Journal of Molecular Catalysis A: Chemical
 |
| ISSN | 1381-1169 |
| Volume | 244Pages:64-67 |
| Abstract | Based on the diversity of ionic liquids, i.e. tunable structure and physicochemical properties, a series of functional ionic liquids and palladium complexes were investigated, and a highly effective catalyst system, Pd(phen)Cl2-BAcImPF6 ionic liquid (phen = 1,10-phenanthroline; BAcIm = 1-butyl-3-acetic acid-imidazolium), was developed for the reductive carbonylation of nitrobenzene to give the corresponding carbamate with higher than 90% of conversion and selectivity at 150 ◦C and 6MPa carbon monoxide. The high catalytic performance is attributed to the acidic function of the BAcImPF6 ionic liquid and the interaction between Pd(phen)Cl2 and the ionic liquid to form the catalytically active palladium complex Pd(phen)2(PF6)2. |
| Keyword | Nitrobenzene Carbon Monoxide Carbonylation Ionic Liquids Palladium Complex |
| Subject Area | 物理化学 |
| Funding Organization | the National Natural Science Foundation of China (No: 20225309) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3670 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Shi F,He YD,Li DM,et al. Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids[J]. Journal of Molecular Catalysis A: Chemical,2006,244:64-67. |
| APA | 石峰,何昱德,李冬梅,马昱博,张庆华,&邓友全.(2006).Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids.Journal of Molecular Catalysis A: Chemical,244,64-67. |
| MLA | 石峰,et al."Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids".Journal of Molecular Catalysis A: Chemical 244(2006):64-67. |
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| 石峰-JMC-A.pdf（142KB） | 开放获取 | License | View Application Full Text | |||
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