Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis | |
Department | 绿色化学与催化研发中心 |
Duan ZY(段志英); Gu YL(顾彦龙); Zhang J(张娟); Zhu LY(朱来英); Deng YQ(邓友全) | |
2006 | |
Source Publication | Journal of Molecular Catalysis A: Chemical |
ISSN | 1381-1169 |
Volume | 250Pages:163-168 |
Abstract | Three new protic ionic liquids based on 2-methylpyridinium were prepared and characterized. Their catalytic activities for the tert-butylation of phenol and the esterification of cyclic olefins with acetic acid were examined and satisfactory results were obtained over 2-methylpyridinium trifluoromethanesulfonate ([2-MPyH]OTf). Hammett method was used to determine the acidity order of these ionic liquids and the results are consistent with the catalytic activities observed in the acid-catalyzed probe reactions. |
Keyword | Protic Ionic Liquids 2-methylpyridinium Hammett Acidity Brønsted Acidity Acid Catalysis |
Subject Area | 物理化学 |
Funding Organization | National Natural Science Foundation of China (nos. 20225309;20533080) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 绿色催化课题组 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/3665 |
Collection | 绿色化学研究发展中心 |
Corresponding Author | Deng YQ(邓友全) |
Recommended Citation GB/T 7714 | Duan ZY,Gu YL,Zhang J,et al. Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis[J]. Journal of Molecular Catalysis A: Chemical,2006,250:163-168. |
APA | 段志英,顾彦龙,张娟,朱来英,&邓友全.(2006).Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis.Journal of Molecular Catalysis A: Chemical,250,163-168. |
MLA | 段志英,et al."Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis".Journal of Molecular Catalysis A: Chemical 250(2006):163-168. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
段志英-JMC-A(2).pdf(211KB) | 开放获取 | License | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment