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Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis
Department绿色化学与催化研发中心
Duan ZY(段志英); Gu YL(顾彦龙); Zhang J(张娟); Zhu LY(朱来英); Deng YQ(邓友全)
2006
Source PublicationJournal of Molecular Catalysis A: Chemical
ISSN1381-1169
Volume250Pages:163-168
AbstractThree new protic ionic liquids based on 2-methylpyridinium were prepared and characterized. Their catalytic activities for the tert-butylation of phenol and the esterification of cyclic olefins with acetic acid were examined and satisfactory results were obtained over 2-methylpyridinium trifluoromethanesulfonate ([2-MPyH]OTf). Hammett method was used to determine the acidity order of these ionic liquids and the results are consistent with the catalytic activities observed in the acid-catalyzed probe reactions.
KeywordProtic Ionic Liquids 2-methylpyridinium Hammett Acidity Brønsted Acidity Acid Catalysis
Subject Area物理化学
Funding OrganizationNational Natural Science Foundation of China (nos. 20225309;20533080)
Indexed BySCI
Language英语
Funding Project绿色催化课题组
Citation statistics
Cited Times:136[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/3665
Collection绿色化学研究发展中心
Corresponding AuthorDeng YQ(邓友全)
Recommended Citation
GB/T 7714
Duan ZY,Gu YL,Zhang J,et al. Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis[J]. Journal of Molecular Catalysis A: Chemical,2006,250:163-168.
APA 段志英,顾彦龙,张娟,朱来英,&邓友全.(2006).Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis.Journal of Molecular Catalysis A: Chemical,250,163-168.
MLA 段志英,et al."Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis".Journal of Molecular Catalysis A: Chemical 250(2006):163-168.
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