| Physicochemical Properties of Nitrile-Functionalized Ionic Liquids | |
| Department | 绿色化学与催化研发中心 |
Zhang QH(张庆华) ; Li ZP(李作鹏); Zhang J(张娟); Zhang SG(张世国); Zhu LY(朱来英); Yang J(杨静); Zhang XP(张晓萍); Deng YQ(邓友全)
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| 2007 | |
| Source Publication | J. Phys. Chem. B
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| ISSN | 1520-6106 |
| Volume | 111Issue:11Pages:2864-2872 |
| Abstract | A series of ionic liquids (ILs) based on nitrile-functionalized imidazolium, pyridinium, and quaternary ammonium as cations and chlorides and tetrafluoroborate, hexafluorophosphate, dicyanamide, and bis- (trifluoromethanesulfonyl)imide as anions have been prepared and characterized. The physicochemical properties such as spectroscopic, thermal, solubility, surface, electrochemical, tribological, and toxic properties were comparatively studied. The results showed that the incorporation of a CN group to cations could result in remarkable changes in these properties. The reason resulting in such remarkable differences in the properties may be attributed to the conformational changes in the imidazolium groups caused by the interaction between the CN group with other neighboring cations or anions and the enhancement in hydrogen-bonding interactions due to the incorporation of a CN group. |
| Subject Area | 物理化学 |
| Funding Organization | the National Natural Science Foundation of China (No. 20533080;20225309;50421502;60377039) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 绿色催化课题 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3651 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Zhang QH,Li ZP,Zhang J,et al. Physicochemical Properties of Nitrile-Functionalized Ionic Liquids[J]. J. Phys. Chem. B,2007,111(11):2864-2872. |
| APA | 张庆华.,李作鹏.,张娟.,张世国.,朱来英.,...&邓友全.(2007).Physicochemical Properties of Nitrile-Functionalized Ionic Liquids.J. Phys. Chem. B,111(11),2864-2872. |
| MLA | 张庆华,et al."Physicochemical Properties of Nitrile-Functionalized Ionic Liquids".J. Phys. Chem. B 111.11(2007):2864-2872. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 张庆华JPC－B.pdf（162KB） | 开放获取 | License | View Application Full Text | |||
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