Access to highly active and thermally stable iron procatalysts using bulky 2-[1-(2,6-dibenzhydryl-4-methylphenylimino)ethyl]-6-[1-rylimino)ethyl]pyridine ligands | |
Department | 羰基合成与选择氧化国家重点实验室 |
Yu JG(余建刚); Liu H(刘浩); Zhang WJ(张文娟); Hao X(郝项); Sun WH(孙文华) | |
2011 | |
Source Publication | Chem. Commun. |
ISSN | 1359-7345 |
Volume | 47Pages:3257-3259 |
Abstract | Ethylene polymerization was performed using a series of 2-[1-(2,6-dibenzhydrylphenylimino)ethyl]-6-[1-(arylimino)ethyl]- pyridyliron(II) chlorides with the activity in the range of 107 g PE mol 1 (Fe) h 1, which is the highest observed in iron procatalysts at elevated reaction temperatures such as 80 1C in the presence of MMAO and 60 1C in the presence of MAO, without any trace of ethylene oligomerization. |
Subject Area | 物理化学 |
Funding Organization | NSFC No. 20874105;MOST 863 program No. 2009AA033601 |
Indexed By | SCI |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/361 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Sun WH(孙文华) |
Recommended Citation GB/T 7714 | Yu JG,Liu H,Zhang WJ,et al. Access to highly active and thermally stable iron procatalysts using bulky 2-[1-(2,6-dibenzhydryl-4-methylphenylimino)ethyl]-6-[1-rylimino)ethyl]pyridine ligands[J]. Chem. Commun.,2011,47:3257-3259. |
APA | 余建刚,刘浩,张文娟,郝项,&孙文华.(2011).Access to highly active and thermally stable iron procatalysts using bulky 2-[1-(2,6-dibenzhydryl-4-methylphenylimino)ethyl]-6-[1-rylimino)ethyl]pyridine ligands.Chem. Commun.,47,3257-3259. |
MLA | 余建刚,et al."Access to highly active and thermally stable iron procatalysts using bulky 2-[1-(2,6-dibenzhydryl-4-methylphenylimino)ethyl]-6-[1-rylimino)ethyl]pyridine ligands".Chem. Commun. 47(2011):3257-3259. |
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