| One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Wang LL(王来来) ; Zhang QS(张勤生); Cui YM(崔玉明)
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| 2011 | |
| Source Publication | Chin. J. Catal.
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| ISSN | 1872-2067 |
| Volume | 32Pages:1143-1148 |
| Abstract | The in situ preparation of the novel chiral catalyst system, which are composed of (S)-2,2',6,6'-tetramethoxy- 4,4'-bis(diphenylphosphine)-3,3'-bipyridine ((S)-P-PHOS) and palladium 2,4-pentanedionate, have been described. These complexes were found to be effective in the asymmetric triple-carbonylation of styrene, reaching up to []D 20 = +27o (c, 0.28, CH2Cl2) for dimethyl 2-oxo-3-phenyl-glutarate using benzoquinone as oxidant, p-toluenesulfonic acid as co-catalyst, and methanol as solvent. |
| Keyword | Styrene Asymmetric Triple-carbonylation Chiral Dimethyl 2-oxo-3-phenyl-glutarate Dipyridlphosphines Palladium 2 4-pentanedionate |
| Subject Area | 有机功能材料 |
| Funding Organization | the National Natural Science Foundation of China (20343005, 20473107, 20673130, 20773147) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 有机功能材料研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/343 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Wang LL(王来来) |
| Recommended Citation GB/T 7714 | Wang LL,Zhang QS,Cui YM. One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene[J]. Chin. J. Catal.,2011,32:1143-1148. |
| APA | 王来来,张勤生,&崔玉明.(2011).One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene.Chin. J. Catal.,32,1143-1148. |
| MLA | 王来来,et al."One-step synthesis of chiral dimethyl 2-oxo-3-phenyl-glutarate in the asymmetric Triple-carbonylation of styrene".Chin. J. Catal. 32(2011):1143-1148. |
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