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CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications
Department固体润滑国家重点实验室
Yan JF(严俊峰)1,2; Ye Q(叶谦)1; Wang XL(王晓龙)1; Yu B(于波)1; Zhou F(周峰)1; Ye Q(叶谦); Zhou F(周峰)
2012
Source PublicationNanoscale
ISSN2040-3364
Volume4Issue:6Pages:2109-2116
AbstractCdS/CdSe quantum dot (QDs) co-sensitized graphene sheets have been obtained via polymer brush templated synthesis. Firstly, the anionic functional polymer (polymethacrylate cadmium) was grafted via the surface initiated atomic transfer radical polymerization (ATRP) using a macromolecular initiator, which contains polymerized pyrene units for chemical anchoring on graphene surface and alkyl bromines to initiate ATRP. Then, the coordinated cadmium in the polymer chains can act as a source precursor for QDs. After reaction, polymer brushes can be recovered and act as the nanoreactor via the absorption of cadmium ions by carboxylate groups. So, high density QDs can be multiply uploaded onto the graphene surface by repeated steps. The as-prepared composite materials exhibited significantly enhanced visible light response compared to plain graphene, and have potential applications as the platform to build solar cell assembles.
Subject Area材料科学与物理化学
DOI10.1039/c2nr11893a
Funding OrganizationNSFC (20973188;21125316);the “Hundred Talents Program” of Chinese Academy of Sciences
Indexed BySCI
If6.233
Language英语
Funding Project材料表面与界面行为研究组
compositor第一作者单位
Citation statistics
Cited Times:38[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/3419
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorYe Q(叶谦); Zhou F(周峰)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Yan JF,Ye Q,Wang XL,et al. CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications[J]. Nanoscale,2012,4(6):2109-2116.
APA Yan JF.,Ye Q.,Wang XL.,Yu B.,Zhou F.,...&周峰.(2012).CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications.Nanoscale,4(6),2109-2116.
MLA Yan JF,et al."CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications".Nanoscale 4.6(2012):2109-2116.
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