CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications | |
Department | 固体润滑国家重点实验室 |
Yan JF(严俊峰)1,2; Ye Q(叶谦)1; Wang XL(王晓龙)1; Yu B(于波)1; Zhou F(周峰)1; Ye Q(叶谦); Zhou F(周峰) | |
2012 | |
Source Publication | Nanoscale |
ISSN | 2040-3364 |
Volume | 4Issue:6Pages:2109-2116 |
Abstract | CdS/CdSe quantum dot (QDs) co-sensitized graphene sheets have been obtained via polymer brush templated synthesis. Firstly, the anionic functional polymer (polymethacrylate cadmium) was grafted via the surface initiated atomic transfer radical polymerization (ATRP) using a macromolecular initiator, which contains polymerized pyrene units for chemical anchoring on graphene surface and alkyl bromines to initiate ATRP. Then, the coordinated cadmium in the polymer chains can act as a source precursor for QDs. After reaction, polymer brushes can be recovered and act as the nanoreactor via the absorption of cadmium ions by carboxylate groups. So, high density QDs can be multiply uploaded onto the graphene surface by repeated steps. The as-prepared composite materials exhibited significantly enhanced visible light response compared to plain graphene, and have potential applications as the platform to build solar cell assembles. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1039/c2nr11893a |
Funding Organization | NSFC (20973188;21125316);the “Hundred Talents Program” of Chinese Academy of Sciences |
Indexed By | SCI |
If | 6.233 |
Language | 英语 |
Funding Project | 材料表面与界面行为研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/3419 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Ye Q(叶谦); Zhou F(周峰) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
Recommended Citation GB/T 7714 | Yan JF,Ye Q,Wang XL,et al. CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications[J]. Nanoscale,2012,4(6):2109-2116. |
APA | Yan JF.,Ye Q.,Wang XL.,Yu B.,Zhou F.,...&周峰.(2012).CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications.Nanoscale,4(6),2109-2116. |
MLA | Yan JF,et al."CdS/CdSe quantum dot co-sensitized graphene nanocomposites via polymer brush templated synthesis for potential photovoltaic applications".Nanoscale 4.6(2012):2109-2116. |
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2109-2116.PDF(977KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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