Preparation and tribological properties of water-soluble copper/silica nanocomposite as a water-based lubricant additive | |
Department | 固体润滑国家重点实验室 |
Zhang CL(张春丽)1; Zhang SM(张晟卯)1,2; Yu LG(余来贵)1; Zhang ZJ(张志军)1; Wu ZS(吴志申)1; Zhang PY(张平余)1; Wu ZS(吴志申); Zhang PY(张平余) | |
2012 | |
Source Publication | Applied Surface Science |
ISSN | 0169-4332 |
Volume | 259Pages:824-830 |
Abstract | Cu/SiO2 nanocomposite was synthesized by sol–gel method. The size, morphology and phase structure of as-prepared Cu/SiO2 nanocomposite were analyzed by means of X-ray diffraction and transmission electron microscopy, and its ultraviolet-visible light spectrum was measured in relation to surface plasmon excitation of Cu particles. The tribological properties of as-synthesized Cu/SiO2 nanocomposite as an additive in distilled water were investigated with a four-ball machine, and the morphology and elemental composition of worn steel surfaces were examined with a scanning electron microscope and an X-ray photoelectron spectroscope. Results show that as-synthesized Cu/SiO2 nanocomposite as a lubricant additive is able to significantly improve the tribological properties of distilled water. A protective and lubricious film composed of Cu and a small amount of FeS, FeSO4 and SiO2 is formed on steel sliding surfaces lubricated by distilled water containing Cu/SiO2 nanocomposite. During friction process Cu nanoparticles can be released from Cu/SiO2 nanocomposite to fill up micro-pits and grooves of steel sliding surfaces, resulting in greatly reduced friction and wear of steel frictional pair via self-repairing. The state and thickness of the film formed on the worn surface is closely related to applied load; and Cu/SiO2 nanocomposite might be a promising water-based lubricant additive for steel-steel contact subjected to moderate load. |
Keyword | Copper Nanoparticles Cu/sio2 Nanocomposite Lubricant Additive Preparation Tribological Properties |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.apsusc.2012.07.132 |
Funding Organization | the National Natural Science Foundation of China (Grant nos. 50975077;21171143);State Key Laboratory of Solid Lubrication Fund (1003) |
Indexed By | SCI |
If | 2.112 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/3306 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Wu ZS(吴志申); Zhang PY(张平余) |
Affiliation | 1.Henan Univ, Key Lab, Minist Educ Special Funct Mat, Kaifeng 475004, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Zhang CL,Zhang SM,Yu LG,et al. Preparation and tribological properties of water-soluble copper/silica nanocomposite as a water-based lubricant additive[J]. Applied Surface Science,2012,259:824-830. |
APA | Zhang CL.,Zhang SM.,Yu LG.,Zhang ZJ.,Wu ZS.,...&张平余.(2012).Preparation and tribological properties of water-soluble copper/silica nanocomposite as a water-based lubricant additive.Applied Surface Science,259,824-830. |
MLA | Zhang CL,et al."Preparation and tribological properties of water-soluble copper/silica nanocomposite as a water-based lubricant additive".Applied Surface Science 259(2012):824-830. |
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824-830.pdf(1730KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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