| Azide anion encapsulation in a tetraurea receptor | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Wang XL(王晓蕾); Jia CD(贾传东); Huang XJ(黄晓卷) ; Wu B(吴彪)
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| 2011 | |
| Source Publication | Inorg. Chem. Commun.
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| ISSN | 1387-7003 |
| Volume | 14Issue:9Pages:1508-1510 |
| Abstract | The azide complex [Na(15-crown-5)]2[L(N3)2] has been synthesized. X-ray single-crystal diffraction analysis revealed that two orthogonally oriented azide anions are encapsulated in one receptor, each by two opposite urea edges of the square tetreurea ligand through N(urea)−H⋯N(azide) hydrogen bonding. UV–vis titration confirmed the 1:2 (host/guest) binding mode in solution with slight bathochromic shifts compared to the ligand. |
| Keyword | Anion Binding Tetraurea Receptors Azide Encapsulation n(Urea)\h⋯n(Azide) Hydrogen Bonding |
| Subject Area | 金属有机 |
| Funding Organization | the National Natural Science Foundation of China (grant no. 20872149) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/317 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Wu B(吴彪) |
| Recommended Citation GB/T 7714 | Wang XL,Jia CD,Huang XJ,et al. Azide anion encapsulation in a tetraurea receptor[J]. Inorg. Chem. Commun.,2011,14(9):1508-1510. |
| APA | 王晓蕾,贾传东,黄晓卷,&吴彪.(2011).Azide anion encapsulation in a tetraurea receptor.Inorg. Chem. Commun.,14(9),1508-1510. |
| MLA | 王晓蕾,et al."Azide anion encapsulation in a tetraurea receptor".Inorg. Chem. Commun. 14.9(2011):1508-1510. |
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